Publications related to Anisotropic node distortions in amorphous MOFs: Low-valent Zr sites as catalytic hotspots

Related publications (10)

Photo-mediated generation of radical synthons from cyclopropanes

Cyclopropanes have emerged as powerful C3 building blocks in organic synthesis. Cyclopropanes serve as precursors to generate reactive intermediates in various total syntheses of natural products and bioactive molecules. Several strategies have been develo ...

EPFL2025

Photogeneration of Hydrogen: Insights from a Pt(II)-Complex Incorporated into a Covalent Organic Framework

Federico De Biasi

Pt(II)-based molecular catalysts stand as a prototypical system in hydrogen evolution reactions (HER) owing to their consistently elevated activity levels. Their integration into heterogeneous systems thus provides an ideal platform to develop catalytic ma ...

Wiley-VCH Verlag2024

N-Containing Carbons Derived from Microporous Coordination Polymers for Use in Post-Combustion Flue Gas Capture

Emad Oveisi, Wendy Lee Queen, Vikram Vinayak Karve, Jordi Espin Marti

Herein, novel carbons that, owing to a high density of micropores (up to 79%) and N-content (up to 14.9%), offering exciting potential for post-combustion CO2 capture are reported. Given that little is known about how starting materials impact the structur ...

WILEY-V C H VERLAG GMBH2023

Fabrication of ZIF-8 membranes by direct assembly of nanosheets from bottom-up synthesis growth solution

Kumar Varoon Agrawal, Heng-Yu Chi, Xuekui Duan

Metal-organic frameworks (MOFs) host intrinsically porous structure and rich structural and chemical features. Several MOFs with pore aperture comparable to the size of gas molecules have attracted interest to form the selective layer of membranes. Synthes ...

ELSEVIER2023

Electronic Regulation of Nickel Single Atoms by Confined Nickel Nanoparticles for Energy-Efficient CO2 Electroreduction

Xile Hu, Andreas Schueler, Anna Krammer, Wenhao Ren

Modulating the electronic structure of atomically dispersed active sites is promising to boost catalytic activity but is challenging to achieve. Here we show a cooperative Ni single-atom-on-nanoparticle catalyst (NiSA/NP) prepared via direct solid-state py ...

Wiley-VCH Verlag GmbH2022

Pyrene-based metal organic frameworks: from synthesis to applications

Berend Smit, Christopher Patrick Ireland, Daniele Ongari, Andres Adolfo Ortega Guerrero, Fatma Pelin Uran

Pyrene is one of the most widely investigated aromatic hydrocarbons given to its unique optical and electronic properties. Hence, pyrene-based ligands have been attractive for the synthesis of metal–organic frameworks (MOFs) in the last few years. In this ...

Royal Society of Chemistry2021

Robust metal-organic frameworks for dry and wet biogas upgrading

Kyriakos Stylianou, Arunraj Chidambaram

Biofuels are considered as viable, sustainable and renewable alternatives to fossil fuels. One amongst them is biomethane which has emerged as one of the valuable contributors in facilitating the essential transition towards green energy sources. Industria ...

ELSEVIER2021

Thermal spin crossover in Fe(ii) and Fe(iii). Accurate spin state energetics at the solid state

Sergio Vela Llausi, Maria Fumanal Quintana

The thermal spin crossover (SCO) phenomenon refers to an entropy-driven spin transition in some materials based on d(6)-d(9) transition metal complexes. While its molecular origin is well known, intricate SCO behaviours are increasingly common, in which th ...

ROYAL SOC CHEMISTRY2020

Charge Separation and Charge Carrier Mobility in Photocatalytic Metal‐Organic Frameworks

Berend Smit, Ivano Tavernelli, Kevin Maik Jablonka, Maria Fumanal Quintana

Metal‐organic frameworks (MOFs) are highly versatile materials owing to their vast structural and chemical tunability. These hybrid inorganic–organic crystalline materials offer an ideal platform to incorporate light‐harvesting and catalytic centers and th ...

2020

Quantum Chemistry Meets Machine Learning

Anne-Clémence Corminboeuf, Alberto Fabrizio, Benjamin André René Meyer, Raimon Fabregat I De Aguilar-Amat

In this account, we demonstrate how statistical learning approaches can be leveraged across a range of different quantum chemical areas to transform the scaling, nature, and complexity of the problems that we are tackling. Selected examples illustrate the ...

SWISS CHEMICAL SOC2019