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In this article, we investigate the effect of prolonged light exposure on silicon heterojunction solar cells. We show that, although light exposure systematically improves solar cell efficiency in the case of devices using intrinsic and p-type layers with optimal thickness, this treatment leads to performance degradation for devices with an insufficiently thick (p) layer on the light-incoming side. Our results indicate that this degradation is caused by a diminution of the (i/p)-layer stack hole-selectivity because of light exposure. Degradation is avoided when a sufficiently thick (p) layer is used, or when exposure of the (p) layer to UV light is avoided, as is the case of the rear-junction configuration, commonly used in the industry. Additionally, applying a forward bias current or an infrared light exposure results in an efficiency increase for all investigated solar cells, independently of the (p)-layer thickness, confirming the beneficial influence of recombination on the performance of silicon heterojunction solar cells.
Nicolas Würsch, Jonathan Emanuel Thomet, Sylvain Dunand
Michael Graetzel, Shaik Mohammed Zakeeruddin, Felix Thomas Eickemeyer, Jovana Milic, Hong Zhang, Ghewa Alsabeh, Marco Alejandro Ruiz Preciado
Christophe Ballif, Alessandro Francesco Aldo Virtuani, Luca Gnocchi