Publication

Molecular Borophosphate Cages

Rosario Scopelliti, Kay Severin, Justus Tönnemann
2013
Journal Articles

Abstract

A synthetic procedure for the synthesis of two molecular borophosphate cages is described. Heating of ethyl phosphate with phenylboronic or 4-formylboronic acid in toluene gives [6+6] condensation products of the general formula EtOPO3BAr. Crystallographic analyses show that the compounds form cages, which can be described as dimers of 12-membered (EtOPO3BAr)(3) macrocycles. The successful incorporation of aldehyde functions on the cage exterior demonstrates that these borophosphates can be decorated with reactive groups.

Official source

https://infoscience.epfl.ch/entities/publication/5ea5448d-d762-4799-a8f6-af2e42e4ec9f

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Molecular Borophosphate Cages

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