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Hydrogenation of bicarbonates in water: By using a ruthenium-based catalytic system hydrogenation of sodium bicarbonate was achieved in water in comparable high TONs and yields. The hydrogenation of sodium bicarbonate takes place with the catalytic system without addition of carbon dioxide.
Anne-Clémence Corminboeuf, Rubén Laplaza Solanas, Shubhajit Das