A Route to Stabilize Uranium(II) and Uranium(I) Synthons in Multimetallic Complexes

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The high stability of the + IVoxidation state limits thorium redox reactivity. Here we report the synthesis and the redox reactivity of two Th(IV) complexes supported by the arene-tethered tris(siloxide) tripodal ligands [(KOSiR2Ar)3-arene)]. The two-elect ...

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The synthesis of heterotrimetallic molecular cages is reported. The assemblies contain three types of coordination compounds: FeII clathrochelate complexes, AuI3(pyrazolate)3 complexes, and [PdII(pyridine)4]2+ complexes. The cages were obtained in a stepwi ...

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A Route to Stabilize Uranium(II) and Uranium(I) Synthons in Multimetallic Complexes

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Two-Electron Redox Reactivity of Thorium Supported by Redox-Active Tripodal Frameworks

Palladium-based supramolecular assemblies: from complex structures to water-soluble anion-receptors

Stepwise synthesis of heterotrimetallic FeII/PdII/AuI coordination cages

Nano onions based on an amphiphilic Au3(pyrazolate)3 complex

Atomic level insight into irradiation effects in nuclear fuel materials

Beyond the coupled distortion model: structural analysis of the single domain cupredoxin AcoP, a green mononuclear copper centre with original features

Implementing Multi-Electron Transfer Strategies in Uranium Chemistry

Tuning the reactivity of uranium towards small molecules in multimetallic complexes

Photochemical [2+2] Cycloaddition of Alkynyl Boronates

Steric and Electronic Effects Responsible for N,O- or N,N-Chelating Coordination of Pyrazolones Containing a Pyridine Ring in Ruthenium Arene Systems

Synthesis and Reactivity of an Anionic Diazoolefin

Mechanism of Reduction of Aqueous U(V)-dpaea and Solid-Phase U(VI)-dpaea Complexes: The Role of Multiheme c-Type Cytochromes

Multielectron Redox Chemistry of Uranium by Accessing the plus II Oxidation State and Enabling Reduction to a U(I) Synthon

Multi-electron Transfer by U(II) and Masked U(II) Complexes

Biostimulation as a sustainable solution for acid neutralization and uranium immobilization post acidic in-situ recovery

Stabilizing Unusual Oxidation States of Lanthanides in Molecular Complexes: Synthesis, Properties, and Reactivity

cell2mol: encoding chemistry to interpret crystallographic data

Development of metal-organic frameworks based on N-heterocyclic ligands

A Mesoionic Diselenolene Anion and the Corresponding Radical Dianion

Computational Studies of the Proton-Coupled Metal Ion Transport in the SLC11/NRAMP Family of Transporters