Publication

The organometallic approach to molecular diversity - halogens as helpers

Manfred Schlosser
2001
Journal Articles

Abstract

A review. Strategies to functionalize simple, though structurally challenging, compds. in regiodivergent manner are outlined. The starting materials are inexpensive (5-500 e/mol) arenes or heterocycles bearing heterosubstituents such as Cl, F, CF3, OCF3, and OMe. A metal is introduced at the targeted position either by direct hydrogen/metal exchange or, if this is not feasible, by use of organometallic precursor species as relay stations. The derivs. thus produced are versatile intermediates that may be employed as building blocks for further elaboration or even as scaffolds in combinatorial synthesis. [on SciFinder (R)]

Official source

https://infoscience.epfl.ch/entities/publication/4a8dbe6e-ab28-4aa2-a37f-5e41e74fd443

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Manfred Schlosser
2001
Journal Articles

Abstract

Official source

https://infoscience.epfl.ch/entities/publication/4a8dbe6e-ab28-4aa2-a37f-5e41e74fd443

About this result

Related concepts (18)

Hydrogen technologies

Hydrogen technologies are technologies that relate to the production and use of hydrogen as a part hydrogen economy. Hydrogen technologies are applicable for many uses. Some hydrogen technologies are carbon neutral and could have a role in preventing climate change and a possible future hydrogen economy. Hydrogen is a chemical widely used in various applications including ammonia production, oil refining and energy. The most common methods for producing hydrogen on an industrial scale are: Steam reforming, oil reforming, coal gasification, water electrolysis.

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Related publications (9)

The organometallic approach to molecular diversity - halogens as helpers

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