Synthesis and equation of state of perovskites in the (Mg, Fe)(3)Al2Si3O12 system to 177 GPa

Chat with Graph Search

Ask any question about EPFL courses, lectures, exercises, research, news, etc. or try the example questions below.

DISCLAIMER: The Graph Chatbot is not programmed to provide explicit or categorical answers to your questions. Rather, it transforms your questions into API requests that are distributed across the various IT services officially administered by EPFL. Its purpose is solely to collect and recommend relevant references to content that you can explore to help you answer your questions.

This thesis is dedicated to developing innovative methodologies that improve elemental quantification in scanning transmission electron microscopy (STEM) using energy-dispersive X-ray spectroscopy (EDXS). The primary motivation stems from a geochemistry pr ...

CsSnI3 is a promising ecofriendly solution for energy harvesting technologies. It exists at room temperature in either a black perovskite polymorph or a yellow 1D double-chain, which irreversibly deteriorates in the air. In this work, we unveil the relativ ...

Hypothesis: The dynamics of colloidal suspension confined within porous materials strongly differs from that in the bulk. In particular, within porous materials, the presence of boundaries with complex shapes entangles the longitudinal and transverse degre ...

The Jahn-Teller (JT) effect involves the ions M with a degenerate electronic state distorting the corner-sharing MO6 octahedra to lift the degeneracy, inducing strong coupling of electrons to lattice, and mediating the exotic properties in perovskite oxide ...

Layered hybrid organic−inorganic perovskite (LHOIP) materials constructed with low-band-gap chromophore-based organic spacer cations are anemerging class of materials that promise unique tunability of their optoelectronic properties. However, the large siz ...

We carried out a series of silicate fractional crystallization experiments at lower mantle pressures using the laser-heated diamond anvil cell. Phase relations and the compositional evolution of the cotectic melt and equilibrium solids along the liquid lin ...

Both seismic observations of dense low shear velocity regions and models of magma ocean crystallization and mantle dynamics support enrichment of iron in Earth’s lowermost mantle. Physical properties of iron-rich lower mantle heterogeneities in the modern ...

Cu-Co-Mn spinel oxide thin films are deposited by reactive magnetron sputtering. The x-ray diffraction (XRD) spectrum suggests a nanocrystalline spinel film when sputtered at approximate to 465 degrees C. In-line scanning tunneling microscopy confirms nano ...

Dielectric elastomers are soft actuators, made of an elastomer membrane sandwiched by compliant electrodes. Because of their high energy density and quick response, they are well suited for dynamic applications such as loudspeakers. Thanks to progress in t ...

It is well established that the lack of understanding the crystallization process in a two-step sequential deposition has a direct impact on efficiency, stability, and reproducibility of perovskite solar cells. Here, we try to understand the solid-solid ph ...

The thicknesss of the brittle lithosphere—the outer portion of a planetary body that fails via fracturing— plays a key role in the geological processes of that body. The properties of both a planet and its host star can influence that thickness, and the po ...

Vapor-based processes are promising options to deposit metal halide perovskite solar cells in an industrial environment due to their ability to deposit uniform layers over large areas in a controlled environment without resorting to the use of (possibly to ...

In this thesis, we exploited optical and X-ray pump-probe methods in a synergistic approach to study the interplay of the electronic, spin and structural degrees of freedom in two class of complex systems relevant for solar energy conversion applications: ...

Over the past decade, remarkable progress has advanced the field of perovskite solar cells to the forefront of thin film solar technologies. The stoichiometry of the perovskite material is of paramount importance as it determines the optoelectronic propert ...

Hybrid halide perovskite materials have become one of the leading candidates for various optoelectronic applications. They are based on organic-inorganic structures defined by the AMX(3) composition, were A is the central cation that can be either organic ...

There is currently an emerging drive towards computational materials design and fabrication of predicted novel materials. One of the keys to developing appropriate fabrication methods is determination of the composition and phase. Here we explore the FeGe ...

Silicon and oxygen are potential light elements in Earth's core because their stronger affinity to metal observed with increasing temperature posits that significant amounts of both can be incorporated into the core. It was proposed that an Fe-Si-O liquid ...

The photovoltaic perovskite, methylammonium lead triiodide [CH3NH3PbI3 (MAPbI(3))], is one of the most efficient materials for solar energy conversion. Various kinds of chemical and physical modifications have been applied to MAPbI(3) towards better unders ...

This article presents a measurement technique and data analysis tool to perform 3D grain distribution mapping and indexing of oligocrystalline samples using neutrons: Laue three-dimensional neutron diffraction (Laue3DND). The approach builds on forward mod ...

Electronic states of iron in the lower mantle's dominant mineral, (Mg,Fe,Al)(Fe,Al,Si)O-3 bridgmanite, control physical properties of the mantle including density, elasticity, and electrical and thermal conductivity. However, the determination of electroni ...

Synthesis and equation of state of perovskites in the (Mg, Fe)(3)Al2Si3O12 system to 177 GPa

Chat with Graph Search

New tools for phase segmentation and denoising of analytical STEM data for enhanced chemical sensitivity, applied to Earth mantle research

First-Principles Thermodynamics of CsSnI3

Active microrheology in corrugated channels: Comparison of thermal and colloidal baths

Anti-Jahn-Teller effect induced ultrafast insulator to metal transition in perovskite BaBiO3

Tuning Napththalenediimide Cations for Incorporation into Ruddlesden–Popper-Type Hybrid Perovskites

Investigating Magma Ocean Solidification on Earth Through Laser‐Heated Diamond Anvil Cell Experiments

Composition and Pressure Effects on Partitioning of Ferrous Iron in Iron-Rich Lower Mantle Heterogeneities

In-line electronic and structural characterization of reactively sputtered Cu-Co-Mn black spinel oxides

Geometric optimization of dielectric elastomer electrodes for dynamic applications

A combined molecular dynamics and experimental study of two-step process enabling low-temperature formation of phase-pure α-FAPbI3

The Effects of Planetary and Stellar Parameters on Brittle Lithospheric Thickness

Vapor Transport Deposition of Methylammonium Iodide for Perovskite Solar Cells

Photo- and thermally-induced electronic and structural dynamics in perovskites and transition metal oxides

Controlling PbI2 Stoichiometry during Synthesis to Improve the Performance of Perovskite Photovoltaics

Layered Hybrid Formamidinium Lead Iodide Perovskites: Challenges and Opportunities

Cubic, hexagonal and tetragonal FeGex phases (x = 1, 1.5, 2): Raman spectroscopy and magnetic properties

Ab Initio Molecular Dynamics Investigation of Molten Fe-Si-O in Earth's Core

Pressure-induced transformation of CH3NH3PbI3: the role of the noble-gas pressure transmitting media

Laue three dimensional neutron diffraction

Effects of composition and pressure on electronic states of iron in bridgmanite