Insights into the microbial reduction of pentavalent and hexavalent uranium species by Shewanella oneidensis MR-1

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Herein, we report the redox reactivity of a multimetallic uranium complex supported by triphenylsiloxide (−OSiPh3) ligands, where we show that low valent synthons can be stabilized via an unprecedented mechanism involving intramolecular ligand migration. T ...

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Uranium isotopic signatures in the rock record are utilized as a proxy for past redox conditions on Earth. However, these signatures display significant variability that complicates the interpretation of specific redox conditions. Using the model uranium-r ...

Thesynthesis of molecular uranium complexes in oxidation stateslower than +3 remains a challenge despite the interest for their multielectrontransfer reactivity and electronic structures. Herein, we report theone- and two-electron reduction of a U(III) com ...

Insights into the microbial reduction of pentavalent and hexavalent uranium species by Shewanella oneidensis MR-1

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A Route to Stabilize Uranium(II) and Uranium(I) Synthons in Multimetallic Complexes

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