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The authors measured the elec. field induced linear dichroism for a wide range of sizes of CdSe nanocrystals. Large ground-state dipole moments were obsd., esp. for the smallest crystals. In these, the authors found a very large anisotropy of the absorption and most of the dipole strength is along the direction of the ground-state dipole moment. For the anisotropy, the authors propose a mechanism for intensity borrowing from intraband transitions, induced by the field of the ground-state dipole moment.
Andras Kis, Gabriele Pasquale, Eloi Régis L Collette, Shun Feng
Emad Oveisi, Aurélien Bornet, Pascal Alexander Schouwink, Sascha Feldmann, Tejas Deshpande, Zachary Andrew Vanorman