Ionic mononuclear [Fe] and heterodinuclear [Fe,Ru] bis (diphenylphosphino)alkane complexes: Synthesis, spectroscopy, DFT structures, cytotoxicity, and biomolecular interactions

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Electron beam-based direct writing of nanostructures using a palladium β-ketoesterate complex

Chinmai Sai Jureddy, Patrik Willi Hoffmann

Gas-assisted focused electron beam-induced deposition (FEBID) as a direct, minimally invasive 3D nanopatterning tool offers many advantages in making nanostructures with complex shapes and novel compositions for evolving nanotechnological applications. In ...

BEILSTEIN-INSTITUT2025

Ligands for metal organic frameworks and a catalyst-free method of making such

Wendy Lee Queen, Ilia Kochetygov

The present invention relates to a catalyst free method for the synthesis of a ligand for polymeric tri-dimensional porous network comprising reacting a. at least one amine of formula (VII), (VIII), (IX), (X) or (XIII), with b. at least one aromatic compou ...

2024

Bridge editing of spin-flip emitters gives insight into excited state energies and dynamics

Sascha Feldmann

Six-coordinate chromium(iii) complexes with high spin-flip (SF) photoluminescence quantum yields and lifetimes (molecular rubies) have attracted huge interest in the past years due to their applicability in sensing, photocatalysis or circularly polarised e ...

ROYAL SOC CHEMISTRY2024

Pivotal Role of Intersite Hubbard Interactions in Fe-Doped alpha-MnO2

Iurii Timrov

We present a first-principles investigation of the structural, electronic, and magnetic properties of the pristine and Fe-doped alpha-MnO2 using density-functional theory with extended Hubbard functionals. The onsite U and intersite V Hubbard parameters ar ...

AMER CHEMICAL SOC2022