Publication

The illusions of spin decoupling

Geoffrey Bodenhausen
1983
Journal Articles

Abstract

The action of heteronuclear decoupling applied to I spins while observing the resonance of a 2nd nuclear species S is examd. for systems prepd. in an arbitrary initial state. Unexpected effects may be produced; the removal of heteronuclear interactions by strong decoupling fields does not guarantee that the 2 spin systems behave independently. In particular, antiphase multiplet magnetization of the S spins remains directly responsive to the radio-frequency I spin perturbation, and to I-I interactions, even when the decoupling removes the heteronuclear coupling interactions completely. Some simple illustrative examples are examd. theor. and exptl. [on SciFinder (R)]

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https://infoscience.epfl.ch/entities/publication/3a1bcea3-8adf-4a3f-bc69-4b428fc5f834

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Geoffrey Bodenhausen
1983
Journal Articles

Abstract

Official source

https://infoscience.epfl.ch/entities/publication/3a1bcea3-8adf-4a3f-bc69-4b428fc5f834

About this result

Related concepts (32)

Solid-state nuclear magnetic resonance

Solid-state NMR (ssNMR) spectroscopy is a technique for characterizing atomic level structure in solid materials e.g. powders, single crystals and amorphous samples and tissues using nuclear magnetic resonance (NMR) spectroscopy. The anisotropic part of many spin interactions are present in solid-state NMR, unlike in solution-state NMR where rapid tumbling motion averages out many of the spin interactions.

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The illusions of spin decoupling

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