Publication

The enigmatic 1J(CH) coupling constants of allyl-type organometallic compounds

Manfred Schlosser
1990
Journal Articles

Abstract

A new attempt has been made to identify the factors responsible for the abnormally small one-bond C, H coupling consts. obsd. for allyl, pentadienyl and heptatrienyl compds. of Li and K. In-plane deformations (widening of the central CCC angle) should have only a small, if not negligible effect. The out-of-plane bending of hydrogen atoms appears to contribute significantly, as probably also does accumulation or polarization of electron d. in conjugated structures. [on SciFinder (R)]

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Manfred Schlosser
1990
Journal Articles

Abstract

Official source

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