Large, heterometallic coordination cages based on ditopic metallo-ligands with 3-pyridyl donor groups

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Dissolution of Fe(III) (hydr)oxide minerals by siderophores (i.e., Fe-specific, biogenic ligands) is an important step in Fe acquisition in environments where Fe availability is low. The observed coexudation of reductants and ligands has raised the questio ...

Hydrogenases are promising templates for constructing new H-2-based catalysts. [Fe]-hydrogenase, which features an ironguanylylpyridinol (FeGP) cofactor, catalyses a reversible hydride transfer from H-2 to methenyl-tetrahydromethanopterin (methenyl-H4MPT+, ...

Understanding how crystalline materials are assembled is important for the rational design of metal-organic frameworks (MOFs). Controlling their formation can allow researchers to streamline the synthesis of new materials as well as control their propertie ...

Dissolution of iron(III)phases is a key process in soils, surface waters, and the ocean. Previous studies found that traces of Fe(II) can greatly increase ligand controlled dissolution rates at acidic pH, but the extent that this also occurs at circumneutr ...

Limiting the increase of CO2 in the atmosphere is one of the largest challenges of our generation(1). Because carbon capture and storage is one of the few viable technologies that can mitigate current CO2 emissions(2), much effort is focused on developing ...

Over the past decades, there has been a dramatic change in the types and amounts of metal ions in the biosphere, since we have introduced huge amount of metal waste into our environment in the course of industrialization of our society. Most of the metal c ...

Metal-organic frameworks (MOFs) are a class of porous materials prepared by the self-assembly of metal ions or clusters with organic ligands. The unique characteristics of MOFs, including structural tunability, high surface areas, low densities and tailore ...

Some nanoporous, crystalline materials possess dynamic constituents, for example, rotatable moieties. These moieties can undergo a conformation change in response to the adsorption of guest molecules, which qualitatively impacts adsorption behavior. We pos ...

Metal–organic frameworks (MOFs), a class of crystalline and porous materials, are synthesized through the self-assembly of organic ligands and inorganic metal nodes (ions or clusters). For the past few years, MOFs have been in the limelight due to their st ...

Nuclear magnetic resonance (NMR) spectroscopy is one of the most powerful and informative methods to probe molecular dynamics. Specifically, chemical exchange is an important phenomenon and one of the earliest and most vigorously investigated in NMR spectr ...

This thesis details the synthesis and characterization of dinuclear clathrochelates functionalized with groups suitable for supramolecular applications. Their successful incorporation into self-assembled discrete and polymeric structures is related. These ...

The complex organizations of amino acid residues on protein surfaces give rise to a wide space of functions for proteins. Great efforts are devoted in biology to understand such structure-property relationships. Many advanced characterization techniques ha ...

Dative boron–nitrogen bonds can be used for the controlled assembly of boronate esters and N-donor ligands. So far, most investigations have focused on crystalline assemblies. In contrast, there are very few reports about soft materials based on dative B–N ...

Metal-organic composites are of great interest for a wide range of applications. The control of their structure remains a challenge, one of the problems being a complex interplay of covalent and supramolecular interactions. This paper describes the self-as ...

This thesis comprises the study of two types of 2D materials, those stabilized by non-covalent and those by covalent interactions. They are synthesized and studied on well-defined metallic surfaces in ultra-high vacuum (UHV). The self-assembly of terephtha ...

Large, heterometallic coordination cages based on ditopic metallo-ligands with 3-pyridyl donor groups

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Low Fe(II) Concentrations Catalyze the Dissolution of Various Fe(III) (hydr)oxide Minerals in the Presence of Diverse Ligands and over a Broad pH Range

The atomic-resolution crystal structure of activated [Fe]-hydrogenase

Synthesis, Characterization, and Applications of Visible Light Active Metal-Organic Frameworks

Fe(II)-Catalyzed Ligand-Controlled Dissolution of Iron(hydr)oxides

Data-driven design of metal-organic frameworks for wet flue gas CO2 capture

Investigation of Key Parameters Affecting Ion-Capturing Abilities of Mixed-Ligand Protected Gold Nanoparticles

Photoluminescent, upconversion luminescent and nonlinear optical metal-organic frameworks: From fundamental photophysics to potential applications

Statistical mechanical model of gas adsorption in porous crystals with dynamic moieties

Electronic metal–organic framework sensors

Study of fast exchanging processes by NMR Spectroscopy

Functionalized Dinuclear Clathrochelates as Supramolecular Building Blocks

Advanced characterization methods for self-assembled organization on nanoparticles

Supramolecular gels based on boronate esters and imidazolyl donors

3D to 2D reorganization of silver-thiol nanostructures, triggered by solvent vapor annealing

On-Surface Assembly and Reactions of Organic Molecules in Ultra-High Vacuum