Introducing rigid pi-conjugated peripheral substituents in phthalocyanines for DSSCs

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In Situ Reflectometry and Diffraction Investigation of the Multiscale Structure of p-Type Polysilicon Passivating Contacts for c-Si Solar Cells

Christophe Ballif, Franz-Josef Haug, Andrea Ingenito, Audrey Marie Isabelle Morisset

The integration of passivating contacts based on a highly doped polycrystalline silicon (poly-Si) layer on top of a thin silicon oxide (SiOx) layer has been identified as the next step to further increase the conversion efficiency of current mainstream cry ...

AMER CHEMICAL SOC2022

Defect Suppression in Oriented 2D Perovskite Solar Cells with Efficiency over 18% via Rerouting Crystallization Pathway

Mohammad Khaja Nazeeruddin, Tom Theodorus Antonius Lummen, Olga Syzgantseva, Yong Ding, Xuehui Liu, Cheng Liu

Vertically oriented 2D perovskites exhibit promising optoelectronic properties and intrinsic stability, but their photovoltaic application is still limited by the low power conversion efficiency (PCE) compared to 3D analogs. Here, a new crystallization pat ...

2021

Palliating the efficiency loss due to shunting in perovskite/silicon tandem solar cells through modifying the resistive properties of the recombination junction

Christophe Ballif, Sylvain Nicolay, Gabriel Christmann, Mathieu Gérard Boccard

As the efficiency of commercial crystalline silicon solar cells approaches its maximum theoretical value, tandem architectures are becoming increasingly popular to continue the push to higher photovoltaic performances. Thin-film materials are particularly ...

2021

Selenophene-Based Hole-Transporting Materials for Perovskite Solar Cells

Mohammad Khaja Nazeeruddin, Maria Cristina Momblona Rincón, Javier Urieta Mora

Two novel and simple donor-pi-bridge-donor (D-pi-D) hole-transporting materials (HTMs) containing two units of the p-methoxytriphenylamine (TPA) electron donor group covalently bridged by means of the 3,4-dimethoxyselenophene spacer through single and trip ...

WILEY-V C H VERLAG GMBH2021

Photoinduced processes in hybrid perovskite for optoelectronics

Valentin Ianis Emmanuel Queloz

Hybrids organic-inorganic perovskite(HOP) solar cells have unequivocally the potential for being a new generation of solar panels with a lower cost and a greater efficiency than well-known silicon solar panels. Today, even if HOPs are seen as one of the be ...

EPFL2021

Implementation and understanding of p plus fired rear hole selective tunnel oxide passivating contacts enabling > 22% conversion efficiency in p-type c-Si solar cells

Christophe Ballif, Sylvain Nicolay, Philippe Wyss, Franz-Josef Haug, Matthieu Despeisse, Andrea Ingenito, Sofia Libraro

Passivating contacts are key enablers for high efficiency c-Si solar cells. Here, we present our latest advancement in terms of implementation and understanding in fired passivating contacts (FPC) used as rear p + passivating contact in p-type solar cells. ...

ELSEVIER2021

Carbazol-phenyl-phenothiazine-based sensitizers for dye-sensitized solar cells

Michael Graetzel, Shaik Mohammed Zakeeruddin, Yi Ding, Wei Huang, Dan Ren, Felix Thomas Eickemeyer, Zhongjin Shen, Yunfei Jiao, Lukas Pfeifer

Heteroaromatic units are commonly used as pi-spacers for sensitizers in dye-sensitized solar cells (DSSCs). Here, we investigated the influence of the pi-spacer on the photophysical properties, electrochemical properties and photovoltaic performance of car ...

Royal Society of Chemistry2021

A recalculation of the efficiency limit in crystalline Si/Si tandem solar cells

Christophe Ballif, Franz-Josef Haug

We determine the limiting efficiency for monolithic tandem solar cells that employ crystalline silicon for the top-cell as well as for the bottom cell. In such a design, the top-cell extends over the region of very high generation rate that forms at the fr ...

2021

Novel photoelectric material of perovskite-like (CH3)(3)SPbI3 nanorod arrays with high stability

Mohammad Khaja Nazeeruddin, Tom Theodorus Antonius Lummen, Wei Liu, Shanshan Xiao, Ruiyuan Hu

Organometallic halide perovskite materials make great achievements in optoelectronic fields, especially in solar cells, in which the organic cations contain amine components. However, the amine with N-H bonds is easily hydrolyzed with moisture in the air, ...

2021

Cyclopentadiene-Based Hole-Transport Material for Cost-Reduced Stabilized Perovskite Solar Cells with Power Conversion Efficiencies Over 23%

Michael Graetzel, Shaik Mohammed Zakeeruddin, Thomas Paul Baumeler, Michael Bauer, Yuhang Liu, Felix Thomas Eickemeyer, Hongwei Zhu

Hole transport materials (HTM) are an important component in perovskite solar cells (PSC). Despite a multitude of HTMs developed in recent years, only few of them lead to solar cells with efficiencies over 20%. Therefore, it is still a challenge to develop ...

2021

Bi-functional interfaces by poly(ionic liquid) treatment in efficient pin and nip perovskite solar cells

Mohammad Khaja Nazeeruddin, Antonio Abate, Giulia Grancini, Filippo de Angelis, Albertus Adrian Sutanto, Pietro Caprioglio, Christian Michael Wolff

Approaches to boost the efficiency and stability of perovskite solar cells often address one singular problem in a specific device configuration. In this work, we utilize a poly(ionic liquid) (PIL) to introduce a multi-functional interlayer to improve the ...

ROYAL SOC CHEMISTRY2021

Electrical Losses Mitigation in Silicon Heterojunction Solar Cells

Laurie-Lou Senaud

To overcome the worldwide challenges of climate change, photovoltaics is foreseen to play a significant role in the world electricity production. Nowadays, single junction crystalline silicon (c-Si) based solar cells hold the largest share of the global ph ...

EPFL2021

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