Publication

Separation of the Oxide and Halide Part in the Oxohalide Fe3Te3O10Cl Due to High Lewis Acidity of the Cations

Helmuth Berger, Dong Zhang
2009
Journal Articles

Abstract

A new iron tellurite halide Fe3Te3O10Cl has been identified that crystallizes in the monoclinic space group P2(1)/c. The crystal structure comprises channels where the Cl ions and also the stereochemically active lone-pair electrons on Te4+ are located. The Cl-atoms rather act as counterions than being part of the covalent/ionic network. The magnetic susceptibility indicates antiferromagnetic ordering below T-N similar to 100 K with a marked splitting of the field cooled (fc) and the zero-field cooled (zfc) susceptibility at low magnetic fields; the splitting disappears at higher magnetic fields. Heat capacity measurements confirm the long-range ordering at below this temperature. Only moderate shifts are observed with Raman spectroscopy at the magnetic transition.

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https://infoscience.epfl.ch/entities/publication/2b517d21-7fec-4160-96cd-90fc96e100b8

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Helmuth Berger, Dong Zhang
2009
Journal Articles

Abstract

Official source

https://infoscience.epfl.ch/entities/publication/2b517d21-7fec-4160-96cd-90fc96e100b8

About this result

Related concepts (32)

Magnetic moment

In electromagnetism, the magnetic moment is the magnetic strength and orientation of a magnet or other object that produces a magnetic field. Examples of objects that have magnetic moments include loops of electric current (such as electromagnets), permanent magnets, elementary particles (such as electrons), composite particles (such as protons and neutrons), various molecules, and many astronomical objects (such as many planets, some moons, stars, etc).

Chloride

The term chloride refers either to a chloride ion (), which is a negatively charged chlorine atom, or a non-charged chlorine atom covalently bonded to the rest of the molecule by a single bond (). Many inorganic chlorides are salts. Many organic compounds are chlorides. The pronunciation of the word "chloride" is ˈklɔəraɪd. The chloride ion is an anion (negatively charged ion) with the charge Cl-. Chloride salts such as sodium chloride are often soluble in water.

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In materials that exhibit antiferromagnetism, the magnetic moments of atoms or molecules, usually related to the spins of electrons, align in a regular pattern with neighboring spins (on different sublattices) pointing in opposite directions. This is, like ferromagnetism and ferrimagnetism, a manifestation of ordered magnetism. The phenomenon of antiferromagnetism was first introduced by Lev Landau in 1933.

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Separation of the Oxide and Halide Part in the Oxohalide Fe3Te3O10Cl Due to High Lewis Acidity of the Cations

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