Publication

Analysis of the Synergistic Effect of Carbonylplatinum Complexes on the Iridium-Catalysed Carbonylation of Methanol to Acetic Acid

Gabor Laurenczy
2006
Journal Articles

Abstract

High-pressure NMR mechanistic investigations into the promoting role of dicarbonyldiiodoplatinum complex in the iridium-catalysed carbonylation of methanol to acetic acid are consistent with iodide abstraction from the [IrI3(CH3)(CO)2]– resting state species by [PtI2(CO)2], unbolting the rate-limiting migratory CO insertion step. A new [Ir–Pt] heterodimetallic complex, which presumably represents the key species involved in the abstraction of I–, has been characterised by NMR in tandem with FAB-MS.

Official source

https://infoscience.epfl.ch/entities/publication/2578bfc6-1c89-402f-9866-16f75da6b74e

About this result

This page is automatically generated and may contain information that is not correct, complete, up-to-date, or relevant to your search query. The same applies to every other page on this website. Please make sure to verify the information with EPFL's official sources.

Graph Chat

Chat with Graph Search

Ask any question about EPFL courses, lectures, exercises, research, news, etc. or try the example questions below.

DISCLAIMER: The Graph Chatbot is not programmed to provide explicit or categorical answers to your questions. Rather, it transforms your questions into API requests that are distributed across the various IT services officially administered by EPFL. Its purpose is solely to collect and recommend relevant references to content that you can explore to help you answer your questions.

Analysis of the Synergistic Effect of Carbonylplatinum Complexes on the Iridium-Catalysed Carbonylation of Methanol to Acetic Acid

Chat with Graph Search

Regioselective Nitration and/or Halogenation of Iridabenzofurans through Electrophilic Substitution

Synthesis and Reactivity of Mononuclear Iron Models of [Fe]-Hydrogenase that Contain an Acylmethylpyridinol Ligand

Cooperative effect between iridium and platinum in the carbonylation of methanol to acetic acid