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The Rayleigh scattering of light at resonance with the ground state exciton transition in quantum wells is studied by means of a microscopic model. The disorder-induced localization of the exciton center-of-mass leads to characteristic features of the scattered intensity which can help understanding the outcome of secondary emission experiments. In particular, the connection between time-resolved scattering and energy-level statistics, and the enhancement of the backscattered intensity in angle-resolved measurements are discussed.