Phase ruleIn thermodynamics, the phase rule is a general principle governing "pVT" systems, whose thermodynamic states are completely described by the variables pressure (p), volume (V) and temperature (T), in thermodynamic equilibrium. If F is the number of degrees of freedom, C is the number of components and P is the number of phases, then It was derived by American physicist Josiah Willard Gibbs in his landmark paper titled On the Equilibrium of Heterogeneous Substances, published in parts between 1875 and 1878.
SyeniteSyenite is a coarse-grained intrusive igneous rock with a general composition similar to that of granite, but deficient in quartz, which, if present at all, occurs in relatively small concentrations (< 5%). It is considered a granitoid. Some syenites contain larger proportions of mafic components and smaller amounts of felsic material than most granites; those are classed as being of intermediate composition. The extrusive equivalent of syenite is trachyte. The feldspar component of syenite is predominantly alkaline in character (usually orthoclase).