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An organic photoredox catalyst, 4CzIPN, was used in combination with a copper catalyst, CuCl, to effect decarboxylative C(sp3)–N coupling. The coupling worked with both anilines and imines as nitrogen sources and could be used to prepare a variety of alkyl amines from readily available alkyl carboxylic acids.
Alexandre Buttler, Pierre Rémi Mariotte, Rodolphe Schlaepfer, Juan Carlos Quezada Rivera, Lucas Georges Jean-Paul Freund
Nicolai Cramer, John Henry Reed