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The prepn. of mesoporous Cr/AlPO was carried out under hydrothermal conditions. The catalyst was characterized by low angle XRD, N-adsorption, diffuse reflectance UV-visible spectroscopy, ESR and thermal anal. The catalytic activity was tested for vapor phase partial oxidn. of toluene with O to benzaldehyde. The catalyst functions both as an acid and redox catalyst. [on SciFinder (R)]