A heterometallic macrocycle as a redox-controlled molecular hinge

Chat with Graph Search

Ask any question about EPFL courses, lectures, exercises, research, news, etc. or try the example questions below.

DISCLAIMER: The Graph Chatbot is not programmed to provide explicit or categorical answers to your questions. Rather, it transforms your questions into API requests that are distributed across the various IT services officially administered by EPFL. Its purpose is solely to collect and recommend relevant references to content that you can explore to help you answer your questions.

Atomic force microscopy (AFM) is a widely used imaging tool for obtaining a variety of information for a range of samples. Although it was initially intended to serve as a method of observing very flat solid surfaces, its use expanded into several other fi ...

Control over synthetic DNA-based nanodevices can be achieved with a variety of physical and chemical stimuli. Actuation with light, however, is as advantageous as difficult to implement without modifying DNA strands with photo-switchable groups. Herein, we ...

This paper investigates the potential impact of deep generative models on the work of creative professionals, specifically focusing on fashion design. We argue that current generative modeling tools lack critical features that would make them useful creati ...

The NLRP3 inflammasome is a central component of the innate immune system. Its activation leads to for-mation of the ASC speck, a supramolecular assembly of the inflammasome adaptor protein ASC. Different models, based on ASC overexpression, have been prop ...

Supramolecular self-assembly in water based on non-covalent bonding is attracting major attention due to the potential of hydrogels and aqueous polymers in biomedical applications. Although supramolecular polymerization in organic solvents is well establis ...

The fabrication of metallic nanostructures on stretchable substrates enables specific applications that exploit the combination of the nano-scale phenomena and the mechanical tunability of the physical dimensions of the nanostructures. Due to the large dif ...

Capillary-assisted particle assembly (CAPA) in predefined topographical templates is a scalable method for the precise positioning of nanoscale objects on various surfaces. High-resolution CAPA templates are typically fabricated by expensive electron-beam ...

Supramolecular assemblies from organic dyes forming J-aggregates are known to exhibit narrowband photoluminescence with full-width at half maximum of approximate to 9 nm (260 cm(-1)). Applications of these high color purity emitters, however, are hampered ...

The work presented in this thesis is focused on the design and discovery of new luminescent, porous, crystalline materials for targeted applications. In particular, we focus on luminescent Metal-Organic Frameworks (MOFs) and Organic Molecules of Intrinsic ...

Supramolecular assemblies with controlled morphology are of paramount importance for energy transport in organic semiconductors. Despite considerable freedom in molecular design, the preparation of dyes that form one dimensional J-aggregates is challenging ...

Two-dimensional (2D) colloidal CdSe nanocrystals (NCs) with precise atomic-scale thickness have attracted intensive attention in recent years due to their optical properties and quantum confinement effects originating from their particular band structure. ...

Understanding hierarchical self-assembly of biological structures requires real time measurement of the self-assembly process over a broad range of length- and timescales. The success of high-speed atomic force microscopy (HS-AFM) in imaging small scale mo ...

Narrow-band photoluminescence (PL) together with high quantum efficiency from organic molecules is essential for high-color-purity emitters. Supramolecular assemblies like J-aggregates are promising materials due to their narrow PL signal with full-width a ...

Modern devices require the tuning of the size, shape and spatial arrangement of nano-objects and their assemblies with nanometre-scale precision, over large-area and sometimes soft substrates. Such stringent requirements are beyond the reach of conventiona ...

Nanofluidic systems offer a huge potential for discovery of new molecular transport and chemical phenomena that can be employed for future technologies. Herein, we report on the transport behavior of surface-reactive compounds in a nanometer-scale flow of ...

Supramolecular assemblies of cyanine dye molecules formed by weak van der Waals forces have gained immense attention for their distinct optical properties (high extinction coefficient, narrow absorption and photoluminescence line-width and small Stokes shi ...

The structure of a biological system defines its function. Therefore, nature has developed sophisticated systems that catalyze chemical reactions that are vital for life on earth. For instance, the photosynthesis is a biological process that is partially r ...

Metal-organic composites are of great interest for a wide range of applications. The control of their structure remains a challenge, one of the problems being a complex interplay of covalent and supramolecular interactions. This paper describes the self-as ...

At the interface between science and engineering, there is the field of biomimicry: Innovations inspired by the observation of natural, evolutionary optimized biological structures and processes. To understand the challenges of biomimicry, the concept of â ...

The newly emerged and quickly growing science of nanotechnology has been recognized as one of ``the twenty-first century's great leaps forward in scientific knowledge''. Self-assembly provides a powerful enabling technique for nanotechnology by providing a ...

A heterometallic macrocycle as a redox-controlled molecular hinge

Chat with Graph Search

Advancements in Nanomechanical Characterization and Biomolecular Imaging with Atomic force Microscopy

Controlling DNA nanodevices with light-switchable buffers

Fashioning the Future: Unlocking the Creative Potential of Deep Generative Models for Design Space Exploration

Nanoscale organization of the endogenous ASC speck

Mechanistic Insight into Supramolecular Polymerization in Water Tunable by Molecular Geometry

Scalable fabrication of functional nanostructures on stretchable substrates by capillary-assisted particle assembly and adhesion lithography

Precise Capillary‐Assisted Nanoparticle Assembly in Reusable Templates

Enhanced Room-Temperature Photoluminescence Quantum Yield in Morphology Controlled J-Aggregates

Luminescent, porous, metal-organic crystals: Design, synthesis, and applications

Excitonic channels from bio-inspired templated supramolecular assembly of J-aggregate nanowirest

Spontaneous Formation of CdSe Photoluminescent Nanotubes with Visible-Light Photocatalytic Performance

Large‐Range HS‐AFM Imaging of DNA Self‐Assembly through In Situ Data‐Driven Control

Exciton Dynamics and Effects of Structural Order in Morphology-Controlled J-Aggregate Assemblies

Self-assembly of nanostructured glass metasurfaces via templated fluid instabilities

Scanning Probe-Directed Assembly and Rapid Chemical Writing Using Nanoscopic Flow of Phospholipids

Exciton Dynamics in 2D Organic Assemblies for Realization of Next-generation Optoelectronic Devices

Design of Surface-Supported Bio-inspired Networks for CO2 and O2 Activation at Room Temperature

3D to 2D reorganization of silver-thiol nanostructures, triggered by solvent vapor annealing

In situ Studies of Peptide and Protein Assemblies at the Solid-Liquid Interface : Hierarchical Self-Assembly, Dynamics and Functional Properties

Design, Modeling, and Control Methods for Fluid-Mediated Programmable Self-Assembly of Resource-Constrained Robotic Modules