Publication

How 2-anilinovinyl perfluoroalkyl ketones can be mechanistically correlated with their cyclization products 2-(perfluoroalkyl)quinolines

Manfred Schlosser
1997
Journal Articles

Abstract

When heated in the presence of phosphoryl chloride, 2-anilinovinyl perfluoroalkyl ketones [e.g., 4-anilino-1,1,1-trifluoro-3-buten-2-one] gave 2-(perfluoroalkyl)quinolines [e.g., 2-(trifluoromethyl)quinoline]. As revealed by cross-over expts., an efficient amine exchange process randomizes the structural component in the final products but not in their aminoenone precursors. 1,3-Diaminoallyl cations (vinylogous formidinium salts) are postulated to act as the turntables. [on SciFinder (R)]

Official source

https://infoscience.epfl.ch/entities/publication/15b1f521-9683-4a37-9e66-2c7748a5f641

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Manfred Schlosser
1997
Journal Articles

Abstract

Official source

https://infoscience.epfl.ch/entities/publication/15b1f521-9683-4a37-9e66-2c7748a5f641

About this result

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How 2-anilinovinyl perfluoroalkyl ketones can be mechanistically correlated with their cyclization products 2-(perfluoroalkyl)quinolines

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