Iron promoted end-on dinitrogen-bridging in heterobimetallic complexes of uranium and lanthanides

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Pyrene-based metal-organic frameworks (MOFs) have tremendous potential for various applications. With infinite structural possibilities, the MOF community often relies on simulations to identify the most promising candidates for given applications. Among t ...

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Diazo compounds of the type R1R2CN2 are widely used in organometallic catalysis and synthetic chemistry. Stable diazoolefins, R1R2C=CN2, have only been isolated recently. Diazoolefins undergo cycloaddition reactions and tend to be carbon donors when used a ...

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Here, we present new cryogenic infrared spectra of the (Imidazole) H-n(+) (n=1,2,3) ions. The data was obtained using helium tagging infrared predissociation spectroscopy. The new results were compared with the data obtained by Gerardi et al. (Chem. Phys. ...

The effect of equilibration time on the composition, structure and solubility of calcium aluminate silicate hydrate (C-A-S-H) was investigated in 0.5 M NaOH solutions at Al/Si = 0.1. Longer equilibration time led to longer silica chains, to less Na and, to ...

Cuboctahedral coordination cages of the general formula [Pd12L24]24+ (L = low-symmetry ligand) were analyzed theoretically and experimentally. With 350 696 potential isomers, the structural space of these assemblies is vast. Orientational self-sorting refe ...

Iron promoted end-on dinitrogen-bridging in heterobimetallic complexes of uranium and lanthanides

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Unraveling metal effects on CO2 uptake in pyrene-based metal-organic frameworks

Realising efficient conversion of nitrogen-containing plastic waste with ceria-based catalysts

Exploring the reactivity of N-heterocyclic diazoolefins

Plasma-activated water retains antimicrobial properties against Escherichia coli after 72 h of storage

Structures of the (Imidazole)(n)H+ ... Ar (n=1,2,3) complexes determined from IR spectroscopy and quantum chemical calculations

Kinetics of Al uptake in synthetic calcium silicate hydrate (C-S-H)

Orientational self-sorting in cuboctahedral Pd cages