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Synergistic Electron-Deficient Surface Engineering: A Key Factor in Dictating Electron Carrier Extraction for Perovskite Photovoltaics

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Multi-electron Transfer by U(II) and Masked U(II) Complexes

Marinella Mazzanti

Complexes of uranium in low oxidation state have shown the ability to activate non-reactive small molecules such as N-2. However, the multi-electron transfer required for such activation remains limited in uranium chemistry. Here, we review our recent rese ...

SWISS CHEMICAL SOC2022

C-Terminal Bioconjugation of Peptides through Photoredox Catalyzed Decarboxylative Alkynylation

Jérôme Waser, Franck Le Vaillant, Marion Marie-Agnès Garreau

We report the first decarboxylative alkynylation of the C-terminus of peptides starting from free carboxylic acids. The reaction is fast, metal-free, and proceeds cleanly to afford alkynylated peptides with a broad tolerance for the C-terminal amino acid. ...

Wiley-VCH Verlag GmbH2019

Photophysics behind highly luminescent two-dimensional hybrid perovskite (CH3(CH2)2NH3)2(CH3NH3)2Pb3Br10 thin films

Anna Fontcuberta i Morral, Luca Francaviglia, Pablo Romero Gómez

Two-dimensional (2D) Ruddlesden–Popper perovskites have emerged as a new class of hybrid materials with high photoluminescence and improved stability compared to their three-dimensional (3D) counterparts. Studies of the photophysics of these new 2D perovsk ...

Royal Society of Chemistry2018

Modulating the Steric, Electronic, and Catalytic Properties of Cp* Ruthenium Half-Sandwich Complexes with β-Diketiminato Ligands

Paul Joseph Dyson, Rosario Scopelliti, Kay Severin, Andrew Douglas Phillips, Katrin Anne Thommes

Five different types of β-diketiminate ligands, bearing electron-donating to strongly electron-withdrawing substituents, were synthesized and used in the synthesis of Cp* ruthenium complexes (Cp* = η5-C5Me5). One series consists of complexes with a covalen ...

American Chemical Society2011