Publication

Cr-poisoning in (La,Sr)(Co,Fe)O-3 cathodes after 10,000 h SOFC stack testing

Jan Van Herle, Aïcha Hessler-Wyser, Zacharie Wuillemin, Josef Andreas Schuler
2012
Journal Articles

Abstract

After 10,000 h solid oxide fuel cell (SOFC) stack operation, the Cr-poisoning situation in (La0.6Sr0.4) (Co0.2Fe0.8)O-3 (LSCF)-based cathode material is depicted in this work. Systematic Cr profiling by energy-dispersive X-ray spectroscopy (EDS), from post-operation samples taken at different locations within the air flow field, reveals Cr accumulation in electrochemically active cathode regions, although the major amount of Cr is trapped in inactive surface-proximal cathode regions; the 20 m LSCF current collector does not fully impede the Cr access to the functional cathode.

Official source

https://infoscience.epfl.ch/entities/publication/0bd08dc5-78f1-42eb-b133-95b2e7511ca2

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Cr-poisoning in (La,Sr)(Co,Fe)O-3 cathodes after 10,000 h SOFC stack testing

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