How Crystallization Additives Govern Perovskite Grain Growth

The preparation of perovskite solar cells from the liquid phase is a cornerstone of their immense potential. However, a clear relationship between the precursor ink and the resulting perovskite is missing. Established theories, such as heterogeneous nucleation and lead complex colloid formation often prove unreliable, which has led to an overreliance on heuristics. Most high-performing perovskites use additives to control crystallization; their role during crystallization is, however, elusive. Here, we provide strong evidence that typical crystallization additives do not predominantly impact the nucleation phase, but rather facilitate coarsening grain growth by increasing ion-mobility across grain boundaries. Drawing from the insights of our unprecedentedly broad study, that combines e and in situ characterization methods, devices and simulations, we propose a concept that proves valid for various additives and perovskite formulations. Moreover, we establish a direct link between additive engineering and perovskite post-processing, offering a unified framework for advancing material design and process engineering.