Publication

Transient behavior of heterogeneous catalytic reactions with educt inhibition

Albert Renken
1986
Journal Articles

Abstract

Under periodic operating conditions, the instantaneous rate of the heterogeneous catalytic addn. of HOAc to ethylene can be an order of magnitude higher than at steady state. A real surface, multistep control model takes into account the strong inhibition of the acid to ethylene sorption and describes the steady state and transient behavior quant. [on SciFinder (R)]

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Albert Renken
1986
Journal Articles

Abstract

Official source

Related concepts (24)

Heterogeneous catalysis

Heterogeneous catalysis is catalysis where the phase of catalysts differs from that of the reactants or products. The process contrasts with homogeneous catalysis where the reactants, products and catalyst exist in the same phase. Phase distinguishes between not only solid, liquid, and gas components, but also immiscible mixtures (e.g. oil and water), or anywhere an interface is present. Heterogeneous catalysis typically involves solid phase catalysts and gas phase reactants.

Catalysis

Catalysis (kəˈtæləsɪs) is the process of change in rate of a chemical reaction by adding a substance known as a catalyst (ˈkætəlɪst). Catalysts are not consumed by the reaction and remain unchanged after it. If the reaction is rapid and the catalyst recycles quickly, very small amounts of catalyst often suffice; mixing, surface area, and temperature are important factors in reaction rate. Catalysts generally react with one or more reactants to form intermediates that subsequently give the final reaction product, in the process of regenerating the catalyst.

Steady state (chemistry)

In chemistry, a steady state is a situation in which all state variables are constant in spite of ongoing processes that strive to change them. For an entire system to be at steady state, i.e. for all state variables of a system to be constant, there must be a flow through the system (compare mass balance). A simple example of such a system is the case of a bathtub with the tap running but with the drain unplugged: after a certain time, the water flows in and out at the same rate, so the water level (the state variable Volume) stabilizes and the system is in a steady state.

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Transient behavior of heterogeneous catalytic reactions with educt inhibition

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