Publication

Recent Advances in Catalytic Enantioselective Rearrangement

Qian Wang, Jieping Zhu, Hua Wu
2019
Reviews

Abstract

Among the fundamental chemical transformations in organic synthesis, rearrangement has been recognized as powerful and reliable reactions for the construction of carbon-carbon or carbon-heteroatom bonds. Benefiting from the advance of the novel catalytic system, catalyst design and activation mode, the chemistry of enantioselective rearrangements has experienced ever-growing development recently and has been successfully used in the synthesis of chiral non-racemic building blocks, natural products, and other valuable compounds. We present herein a survey of the recent development on the catalytic enantioselective rearrangement (from 2013 onward) organized according to the rearrangement type.

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https://infoscience.epfl.ch/entities/publication/03c728ce-ef66-4c86-8616-02cd7629e6ff

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Qian Wang, Jieping Zhu, Hua Wu
2019
Reviews

Abstract

Official source

https://infoscience.epfl.ch/entities/publication/03c728ce-ef66-4c86-8616-02cd7629e6ff

About this result

Related concepts (32)

Carbon

Carbon () is a chemical element with the symbol C and atomic number 6. It is nonmetallic and tetravalent—its atom making four electrons available to form covalent chemical bonds. It belongs to group 14 of the periodic table. Carbon makes up about 0.025 percent of Earth's crust. Three isotopes occur naturally, ^12C and ^13C being stable, while ^14C is a radionuclide, decaying with a half-life of about 5,730 years. Carbon is one of the few elements known since antiquity.

Carbon–hydrogen bond

In chemistry, the carbon-hydrogen bond ( bond) is a chemical bond between carbon and hydrogen atoms that can be found in many organic compounds. This bond is a covalent, single bond, meaning that carbon shares its outer valence electrons with up to four hydrogens. This completes both of their outer shells, making them stable. Carbon–hydrogen bonds have a bond length of about 1.09 Å (1.09 × 10−10 m) and a bond energy of about 413 kJ/mol (see table below). Using Pauling's scale—C (2.55) and H (2.

Noble gas compound

In chemistry, noble gas compounds are chemical compounds that include an element from the noble gases, group 18 of the periodic table. Although the noble gases are generally unreactive elements, many such compounds have been observed, particularly involving the element xenon. From the standpoint of chemistry, the noble gases may be divided into two groups: the relatively reactive krypton (ionisation energy 14.0 eV), xenon (12.1 eV), and radon (10.7 eV) on one side, and the very unreactive argon (15.

Related publications (31)

Recent Advances in Catalytic Enantioselective Rearrangement

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