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Friction and wear are important phenomena occurring in all devices with moving parts. While their origin and the way they evolve over time are not fully understood, they are both intimately linked to surface roughness. Guided by pin-on-disc experiments, we present the steps giving rise to the formation of surface roughness on silica, first by the creation of roughly spherical wear particles whose size is related to a critical length scale governing the transition between ductile and brittle behavior, then by the accumulation of these small particles into a larger third body layer, or gouge. We show that, for the explored range of loading conditions, the surface roughness evolves toward a common steady state under unlubricated wear regardless of the initial surface roughness, hinting toward the possible predictability of roughness evolution in wearing components. The friction coefficient is shown to be related to the surface roughness and its time evolution is discussed as well.