Publication

Thiazolium carbene catalysts for the fixation of CO2 onto amines

Paul Joseph Dyson, Felix Daniel Bobbink, Safak Bulut, Shoubhik Das
2016
Journal Articles

Abstract

The catalytic N-formylation and N-methylation of amines using CO2 as the carbon source represents a facile and sustainable approach for the synthesis of pharmaceuticals and natural products. Herein, we describe highly effective and inexpensive thiazolium carbene-based catalysts derived from vitamin B1 for the N-formylation and N-methylation of amines, using polymethylhydrosiloxane (PMHS) as a reducing agent, which operate under ambient conditions.

Official source

https://infoscience.epfl.ch/entities/publication/00d8c9a9-d456-40f4-adca-6b38d6557c9d

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Thiazolium carbene catalysts for the fixation of CO2 onto amines

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