Publications by Fang-Che Hsueh

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Uranium nitride compounds are important molecular analogues of uranium nitride materials such as UN and UN2 which are effective catalysts in the Haber-Bosch synthesis of ammonia, but the synthesis of molecular nitrides remains a challenge and studies of th ...

Over the past few decades, low oxidation state f-element molecular complexes, including those of lanthanide, uranium, and thorium, have demonstrated high reactivity towards small molecules such as N2 and CO2 due to their unique chemical properties. However ...

Synthetic strategies to isolate molecular complexes of lanthanides, other than cerium, in the +4 oxidation state remain elusive, with only four complexes of Tb(iv) isolated so far. Herein, we present a new approach for the stabilization of Tb(iv) using a s ...

Single-atom (group 15 and group 16 anions) bridged dimetallic complexes of low oxidation state uranium provide a convenient route to implement multielectron transfer and promote magnetic communication in uranium chemistry, but remain extremely rare. Here w ...

The high stability of the + IVoxidation state limits thorium redox reactivity. Here we report the synthesis and the redox reactivity of two Th(IV) complexes supported by the arene-tethered tris(siloxide) tripodal ligands [(KOSiR2Ar)3-arene)]. The two-elect ...

The chemistry of lanthanides is limited to one electron transfer reactions due to the difficulty of accessing multiple oxidation states. Here we report that a redox-active ligand combining three siloxides with an arene ring in a tripodal ligand can stabili ...

Fang-Che Hsueh

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Synthesis, structure, and reactivity of uranium(VI) nitrides

Designing Complexes of f-elements Capable of Multielectron Transfer Reactivity

Siloxide tripodal ligands as a scaffold for stabilizing lanthanides in the +4 oxidation state

Synthesis, structure and redox properties of single-atom bridged diuranium complexes supported by aryloxides

Two-Electron Redox Reactivity of Thorium Supported by Redox-Active Tripodal Frameworks

Isolation and redox reactivity of cerium complexes in four redox states