Dieuwertje Katelijn Modder

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In the last decades, the activation of small molecules has attracted increasing attention for their use as cheap and abundant feedstock. Low-oxidation state uranium complexes have displayed high reactivity towards small molecules thanks to their unique pro ...

Oxide is an attractive linker for building polymetallic complexes that provide molecular models for metal oxide activity, but studies of these systems are limited to metals in high oxidation states. Herein, we synthesized and characterized the molecular an ...

Herein, we report the redox reactivity of a multimetallic uranium complex supported by triphenylsiloxide (−OSiPh3) ligands, where we show that low valent synthons can be stabilized via an unprecedented mechanism involving intramolecular ligand migration. T ...

Radical-bridged diuranium complexes are desirable for their potential high exchange coupling and single molecule magnet (SMM) behavior, but remain rare. Here we report for the first time radical-bridged diuranium(IV) and diuranium(III) complexes. Reaction ...

The redox chemistry of uranium is dominated by single electron transfer reactions while single metal four-electron transfers remain unknown in f-element chemistry. Here we show that the oxo bridged diuranium(iii) complex K(2.2.2-cryptand)[{((Me3Si)(2) ...

Dieuwertje Katelijn Modder

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Implementing Multi-Electron Transfer Strategies in Uranium Chemistry

Delivery of a Masked Uranium(II) by an Oxide-Bridged Diuranium(III) Complex

A Route to Stabilize Uranium(II) and Uranium(I) Synthons in Multimetallic Complexes

Assembling diuranium complexes in different states of charge with a bridging redox-active ligand

Single metal four-electron reduction by U(II) and masked "U(II)" compounds

Accessing a Highly Reducing Uranium(III) Complex through Cyclometalation