Andrew Francis Dalebrook

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We present here the results of our investigation on aqueous phase formic acid (FA) dehydrogenation using non-noble metal based pre-catalysts. This required the synthesis of m-trisulfonated-tris[2-(diphe nylphosphino)ethyl]phosphine sodium salt (PP3TS) as a ...

Regioselective electrophilic substitution reactions of the iridabenzofurans [Ir(C7H5O{OMe-7})(CO)(PPh3)(2)]-[OTf] (1) and IrCl(C7H5O{OMe-7})(PPh3)(2) (2) provide a convenient route to mononitro-, dinitro-, and mixed nitro-/halo- substituted derivatives. Tr ...

Water-soluble ruthenium m-triphenylphosphinetrisulfonate (TPPTS) complexes are excellent catalysts for formic acid dehydrogenation. Interestingly, the choice of metal catalyst precursor has a direct influence on initial activities. The reaction with hexaaq ...

The efficient storage of hydrogen is one of three major hurdles towards a potential hydrogen economy. This report begins with conventional storage methods for hydrogen and broadly covers new technology, ranging from physical media involving solid adsorbent ...

Aqueous solutions of cesium formate and bicarbonate repre- sent an effective hydrogen storage–delivery couple that under- goes either release or take up of hydrogen in the presence of {RuCl2(mTPPTS)2}2 (TPPTS = triphenylphosphine trisulfonate) and excess m ...

Andrew Francis Dalebrook

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Quantitative aqueous phase formic acid dehydrogenation using iron(II) based catalysts

Regioselective Nitration and/or Halogenation of Iridabenzofurans through Electrophilic Substitution

Formic Acid Dehydrogenation Catalysed by Tris(TPPTS) Ruthenium Species: Mechanism of the Initial "Fast" Cycle

Hydrogen storage: beyond conventional methods

A Viable Hydrogen Storage and Release System Based on Cesium Formate and Bicarbonate Salts: Mechanistic Insights into the Hydrogen Release Step