Thomas James Stockmann

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The oxygen reduction reaction by decamethylferrocene (DMFc), triggered by hydrophilic metallic cations behaving as Lewis acids towards water molecules in a homogeneous organic phase reaction, was investigated using cyclic voltammetry at the water|1,2-dichl ...

The complexation reactions between strontium (Sr2+) and octyl(phenyl)-N,N-diisobutylcarbamoylmethylphosphine oxide (CMPO) were studied at the aqueous vertical bar 1,2-dichloroethane (w vertical bar DCE) and aqueous vertical bar room-temperature ionic liqui ...

A room temperature ionic liquid (IL) composed of a quaternary alkylphosphonium (trihexyltetradecylphosphonium, P66614(+)) and tetrakis(pentafluorophenyl) borate anion (TB) was employed within a water| P66614TB (w|P66614TB or w|IL) biphasic system to evalua ...

The formation and the dissociation of metal hydrides are key steps within the hydrogen evolution reaction (HER) pathway for photochemical water splitting, but also impacts a wide range of other catalytic, industrial, and biochemical reactions. Herein, we d ...

Herein is reported the determination of the Gibbs energy of dioxouranium (UO22+) transfer across an interface between two immiscible electrolytic solutions (ITIES), water and 1,2-dichloroethane, that was supported at a 25 mu m diameter microhole, by means ...

The present work describes the application of scanning electrochemical microscopy (SECM) in the feedback mode to determine the kinetics of oxygen reduction at or near the liquid/liquid interface – between water and 1,2-dichloroethane (w/DCE). The system co ...

The mechanism of the oxygen reduction reaction (ORR) at a liquid|liquid interface, employing ferrocene (Fc) derivatives – such as decamethylferrocene (DMFc) – as a lipophilic electron donor along with sulfuric acid as an aqueous proton source, was elucidat ...

Lithium cations are shown to have a significant role on catalyzing oxygen and proton reduction along with SN1 reactions in biphasic systems. We propose that this catalytic effect is due to the surprising acidity of the hydrated cations; interactions betwee ...

Thomas James Stockmann

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Electrochemical oxygen reduction at soft interfaces catalyzed by the transfer of hydrated lithium cations

Interfacial Complexation Reactions of Sr2+ with Octyl(phenyl)-N,N-diisobutylcarbamoylmethylphosphine Oxide for Understanding Its Extraction in Reprocessing Spent Nuclear Fuels

Electrochemical assessment of water|ionic liquid biphasic systems towards cesium extraction from nuclear waste

Decamethylruthenocene Hydride and Hydrogen Formation at Liquid|Liquid Interfaces

Evaluation of Gibbs Energy of Dioxouranium Transfer at an Electrified Liquid vertical bar Liquid Interface Supported on a Microhole

Kinetic differentiation of bulk/interfacial oxygen reduction mechanisms at/near liquid/liquid interfaces using scanning electrochemical microscopy

Mechanism of oxygen reduction by metallocenes near liquid|liquid interfaces

Surprising acidity of hydrated lithium cations in organic solvents