Publications by Ivica Zivkovic

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In today's technology, the need for data-and energy storage devices with a high efficiency and capacity, as well as a high writing speed for the former is ever increasing. For such applications, materials with a magnetic nature, i.e. Ferro-, Ferri-and Anti ...

The role of alkali promoters in N-2 cleavage by metal complexes remains poorly understood despite its relevance to the industrial production of ammonia from N-2. Here we report a series of alkali bound-oxo-bridged diuranium(iii) complexes that provide a un ...

We report a small-angle neutron scattering study of the helical and skyrmion lattice order in single-crystal Cu2OSeO3 under quasihydrostatic helium gas pressures up to 5 kbar. By using helium gas as the pressure-transmitting medium (PTM) we ensure pressure ...

Transition-metal dichalcogenides (TMDs) are layered compounds that support many electronic phases, including various charge density waves, superconducting, and Mott insulating states. Their intercalation with magnetic ions introduces magnetic sublayers, wh ...

Murunskite (K 2 FeCu 3 S 4 ) bridges the two known families of high‐temperature superconductors, cuprates and iron‐pnictides, structurally and electronically. Like these families, murunskite exhibits an antiferromagnetic (AF)‐like response with an ordered ...

Molecular uranium nitride complexes were prepared to relate their small molecule reactivity to the nature of the U & xe001;N & xe001;U bonding imposed by the supporting ligand. The U4+-U4+ nitride complexes, [NBu4][{(((BuO)-Bu-t)(3)SiO)(3)U}(2)(mu-N)], [NB ...

The discovery of multiple coexisting magnetic phases in the crystallographically homogeneous compound Ca3Co2O6 has stimulated ongoing research activity. In recent years the main focus has been on the zero-field-state properties, where exceedingly long time ...

Quantum spin liquids are exotic states of matter that form when strongly frustrated magnetic interactions induce a highly entangled quantum paramagnet far below the energy scale of the magnetic interactions. Three-dimensional cases are especially challengi ...

Despite their synthetic interest and potential attractive properties, the preparation of heteroleptic U(III) complexes containing monodentate ligands remains challenging. Here we report the synthesis, structure and magnetic properties of three heteroleptic ...

Co3Sn2S2 has recently been predicted to be a Weyl semimetal in which magnetic order is key to its behavior as a topological material. Here, we report unpolarized neutron diffraction and spherical neutron polarimetry measurements, supported by magnetization ...

Lanthanides (Ln) usually occur in the +3, or more recently the +2, oxidation states. The only example of an isolated molecular Ln(4+) so far remains Ce4+. Here we show that the +4 oxidation state is also accessible in a molecular compound of terbium as dem ...

The well-defined catalytic conversion of dinitrogen (N2) to ammonia (NH3) by molecular complexes is of fundamental interest and important for providing an atomic-level understanding of reactivity that can be related to industrial and biological nitrogen-fi ...

We report a detailed single-crystal investigation of a magnetoelectric ferrimagnet Cu2OSeO3 using dc magnetization and ac susceptibility along the three principal directions [100], [110], and [111]. We have observed that in small magnetic fields two magnet ...

The recent discovery of topologically nontrivial behavior in Co3Sn2S2 stimulated a notable interest in this itinerant ferromagnet (T-C = 174 K). The exact magnetic state remains ambiguous, with several reports indicating the existence of a second transitio ...

Synthetic strategies to isolate molecular complexes of lanthanides, other than cerium, in the +4 oxidation state remain elusive, with only four complexes of Tb(iv) isolated so far. Herein, we present a new approach for the stabilization of Tb(iv) using a s ...

Quantum magnets display a wide variety of collective excitations, including spin waves (magnons), coherent singlet-triplet excitations (triplons), and pairs of fractional spins (spinons). These modes differ radically in nature and properties, and in all co ...

Out of the 14 lanthanide (Ln) ions, molecular complexes of Ln(IV) were known only for cerium and more recently terbium. Here we demonstrate that the +IV oxidation state is also accessible for the large praseodymium (Pr) cation. The oxidation of the tetraki ...

We examine the role of charge, structural, and spin degrees of freedom in the previously poorly understood phase transition in the 5d1 transition-metal double perovskite Cs2TaCl6 using a combination of computational and experimental techniques. Our heat ca ...

Herein, we report the redox reactivity of a multimetallic uranium complex supported by triphenylsiloxide (−OSiPh3) ligands, where we show that low valent synthons can be stabilized via an unprecedented mechanism involving intramolecular ligand migration. T ...

We report on the design and characterization of single-chip electron spin resonance (ESR) detectors operating at 50 GHz, 92 GHz, and 146 GHz. The core of the single-chip ESR detectors is an integrated LC-oscillator, formed by a single turn aluminum planar ...

Ivica Zivkovic

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Reinvestigation of the Crystal Structure and Magnetic Properties of M(vo)2(po4)24h2o and Ni0.5(vo)2(po4)21.5h2o (m = Ni2+, Co2+) Compounds

Cation assisted binding and cleavage of dinitrogen by uranium complexes

In situ control of the helical and skyrmion phases in Cu2OSeO3 using high-pressure helium gas up to 5 kbar

Electronic transport and magnetism in the alternating stack of metallic and highly frustrated magnetic layers in Co(1/3)NbS(2)

High‐Entropy Magnetism of Murunskite

Tuning the structure, reactivity and magnetic communication of nitride-bridged uranium complexes with the ancillary ligands

Magnetic dynamics across the in-field transition in Ca3Co2O6

Magnetic Field Induced Quantum Spin Liquid in the Two Coupled Trillium Lattices of K2Ni2(SO4)(3)

Structure and Magnetic Properties of a Series of Uranium Bis-Siloxide Complexes

Magnetic structure of the topological semimetal Co3Sn2S2

Molecular Complex of Tb in the +4 Oxidation State

Catalytic and stoichiometric stepwise conversion of side-on bound dinitrogen to ammonia mediated by a uranium complex

Two-step transition in a magnetoelectric ferrimagnet Cu2OSeO3

Unraveling the origin of the peculiar transition in the magnetically ordered phase of theWeyl semimetal Co3Sn2S2

Siloxide tripodal ligands as a scaffold for stabilizing lanthanides in the +4 oxidation state

Triplons, magnons, and spinons in a single quantum spin system: SeCuO3

Accessing the plus IV Oxidation State in Molecular Complexes of Praseodymium

Charge multipole correlations and order in Cs2TaCl6

A Route to Stabilize Uranium(II) and Uranium(I) Synthons in Multimetallic Complexes

Single-chip electron spin resonance detectors operating at 50 GHz, 92 GHz, and 146 GHz