Publications by Etienne Baranoff

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The invention relates to electrochemical devices comprising complexes of cobalt comprising at least one ligand with a 5- or six membered, N-containing heteroring. The complex are useful as p- and n- dopants, as over of electrochemical devices, in particula ...

The invention relates to electrochemical devices comprising complexes of cobalt comprising at least one ligand with a 5- or six membered, N-containing heteroring. The complex are useful as p- and n-dopants, as over of electrochemical devices, in particular ...

In solid-state dye-sensitized solar cells (ssDSCs), the poor pore filling of the mesoporous semiconductor and the short diffusion length of charge carriers, in the hole-transport material (HTM) have limited the mesoscopic titania layer to a thickness of 2- ...

Running relay: Incorporating an energy-relay dye (ERD) into the hole transporter of a dye-sensitized solar cell increased power-conversion efficiency by 29 % by extending light harvesting into the blue region. In the operating mechanism (see picture), abso ...

The dye-sensitized mesoscopic solar cell has been intensively investigated as a promising photovoltaic cell. Its ecological and economical fabrication processes make it attractive and credible alternative to conventional photovoltaic systems. In contrast t ...

This brief review describes applications of cyclometallated iridium complexes for energy saving organic light-emitting devices (OLED's) and energy generating molecular photovoltaic cells. The first part consists of a short overview of the methods to modula ...

Bis-cyclometalated cationic Ir(III) diimine complexes Ir((CN)-N-Lambda)2((NN)-N-Lambda) with 1-phenylpyrazoles ((CN)-N-Lambda) and 1-(4'-tert-butyl-2'-pyridyl) pyrazole ((NN)-N-Lambda) are white solids that have absorption onset below 425 nm and ele ...

Panchromatic response is essential to increase the light-harvesting efficiency in solar conversion systems. Herein we show increased light harvesting from using multiple energy relay dyes inside dye-sensitized solar cells. Additional photoresponse from 400 ...

A library of emission spectra of 90 bis-cyclometallated iridium complexes has been obtained using a simple combinatorial approach performed at room temperature. Trends in emission maxima are rationalized using Hammett parameters and invoking inter ligand e ...

The aim of this brief review is to give a short and simple overview of the dye-sensitized solar cell technology from the working principles to the first commercial applications. It emphasizes the role of the sensitizer and the strategies to improve the per ...

We report here a new cationic bis-cyclometallated iridium(III) complex, 1, with deep-blue emission at 440 nm and its use in Light-emitting Electrochemical Cells (LECs). The design is based on the 2',6'-difluoro-2,3'-bipyridine skeleton as the cyclometallat ...

A simple mononuclear cyclometallated iridium(III) complex exhibits white photo- and electro-luminescence in the wavelength range from 440 to 800 nm, which originates from a single emitting excited state of mixed character. ...

We report the first bis-cyclometalated cationic iridium(III) complex with N-aryl-substituted 1H-imidazo [4,5-f][1,10]phenanthroline. The complex emits yellow-orange phosphorescence with a maximum at 583 nm, a quantum yield of 43%, and an excited-state life ...

Herein, we present the first use of a gallium oxide tunnelling layer to significantly reduce electron recombination in dye-sensitized solar cells (DSC). The sub-nanometer coating is achieved using atomic layer deposition (ALD) and leading to a new DSC reco ...

Isomerization of a neutral bis-cyclometalated iridium(III) complex has been observed for the first time during the preparation of vacuum-processed organic light-emitting devices (OLEDs) and reproduced in solution. Isolation of the isomer revealed a cis org ...

Energy transfer from phosphorescent ruthenium complex N877 dissolved in the liquid electrolyte to the squaraine sensitizer SQ1 anchored on the titanium oxide surface resulted in a four fold increase in external quantum efficiency in the blue part of the vi ...

The behavior toward oxygen sensing of nanocomposites made of the aluminum oxide-hydroxide nanostructured solid support (AP200/19) and neutral blue emitting cyclometalated iridium(III) complexes was studied. The results are compared with the same dyes immob ...

The present invention provides an improved redox couple for electrochemical and optoelectronic devices. The redox couple is based on a complex of a first row transition metal, said complex containing at least one mono-, bi-, or tridentate ligand comprising ...

The recently reported heteroleptic cyclometallated iridium(III) complex [Ir(2-phenylpyridine)(2)(2-carboxy-4-dimethylaminopyridine)] N984 and its isomer N984b have been studied more in detail. While photo- and electrochemical properties are very similar, D ...

Etienne Baranoff

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Cyclometallated Iridium Complexes as Sensitizers for Dye-Sensitized Solar Cells

Metal complexes for use as dopants and other uses

Metal complex used as dopant and other usage

Influence of Donor Groups of Organic D-pi-A Dyes on Open-Circuit Voltage in Solid-State Dye-Sensitized Solar Cells

Panchromatic Response in Solid-State Dye-Sensitized Solar Cells Containing Phosphorescent Energy Relay Dyes

Panchromatic engineering for dye-sensitized solar cells

Cyclometallated iridium complexes for conversion of light into electricity and electricity into light

Charged cyclometalated iridium(III) complexes that have large electrochemical gap

Incorporating Multiple Energy Relay Dyes in Liquid Dye-Sensitized Solar Cells

Room-temperature combinatorial screening of cyclometallated iridium(III) complexes for a step towards molecular control of colour purity

Dye-sensitized solar cells: A brief overview

A deep-blue emitting charged bis-cyclometallated iridium(III) complex for light-emitting electrochemical cells

White-light phosphorescence emission from a single molecule: application to OLED

Efficient orange light-emitting electrochemical cells

Sub-nanometer Ga2O3 tunnelling layer by atomic layer deposition to achieve 1.1V open-circuit potential in dye-sensitized solar cells

Sublimation Not an Innocent Technique: A Case of Bis-Cyclometalated Iridium Emitter for OLED

Phosphorescent energy relay dye for improved light harvesting response in liquid dye-sensitized solar cells

Nanocomposites containing neutral blue emitting cyclometalated iridium(III) emitters for oxygen sensing

Redox couple for electrochemical and optoelectronic devices

An inconvenient influence of iridium(III) isomer on OLED efficiency