Publications by Andrea Cannizzo

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Ultrafast electronic-vibrational relaxation upon excitation of the singlet charge-transfer b1A' state of [Re(L)(CO)3(bpy)]n (L = Cl, Br, I, n = 0; L = 4-Et-pyridine, n = 1+) in acetonitrile was investigated using the femtosecond fluorescence up-conversion ...

The transfer of charge at the molecular level plays a fundamental role in many areas of chemistry, physics, biology and materials science. Today, more than 60 years after the seminal work of R. A. Marcus, charge transfer is still a very active field of res ...

Femtosecond fluorescence up-conversion, UV-Vis and IR transient absorption spectroscopy are used to study the photo-isomerization dynamics of a new type of zwitterionic photoswitch based on a N-alkylated indanylidene pyrroline Schiff base framework (ZW-NAI ...

Intermolecular electron-transfer reactions have a crucial role in biology, solution chemistry and electrochemistry. The first step of such reactions is the expulsion of the electron to the solvent, whose mechanism is determined by the structure and dynamic ...

UV-Vis absorption spectra of one-electron reduction products and (MLCT)-M-3 excited states of [(ReCl)-Cl-I(CO)(3)-(N, N)] (N, N = 2,2'-bipyridine, bpy; 1,10-phenanthroline, phen) have been measured by low-temperature spectroelectrochemistry and UV-Vis tran ...

We report on an experimental study with UV and visible ultrafast time-gated emission and transient absorption of the early photodynamics of horse heart Cytochrome c in both ferric and ferrous redox states. A clear separation in time and energy of tryptopha ...

We present a femtosecond broad-band fluorescence up-conversion study of the vibrational relaxation dynamics of two UV chromophores, 2,5-diphenyloxazole (PPO) and para-terphenyl (pTP), pumped with a large excess of vibrational energy (>2000 cm(-1)). The ban ...

Ultrafast transient absorption spectroscopy of wild-type bacteriorhodopsin (WT bR) and 2 tryptophan mutants (W86F and W182F) is performed with visible light excitation (pump) and UV probe. The aim is to investigate the photoinduced change in the charge dis ...

Femto- to picosecond excited-state dynamics of the complexes Re(L)(CO)(3)(N,N) (N,N = bpy, phen, 4,7-dimethyl-phen (dmp); L = Cl, n = 0; L = imidazole, n = 1+) were investigated using fluorescence up-conversion, transient absorption in the 650-285 nm ...

Using broadband UV-vis femtosecond transient absorption and fluorescence up-conversion, we investigate the interaction between the haem moiety of ferric and ferrous Horse heart Cytochrome c and its single Tryptophan (Trp) residue and the energy dissipation ...

Dizzy cooling: Femtosecond excitation of the singlet states of aqueous [FeII(bpy)3]2+ (bpy=2,2-bipyridine) leads to the formation of a vibrationally hot quintet state that exhibits wave-packet dynamics arising from a chelate-ring and bending mode. The vibr ...

Femtosecond white-light continuum probe transient absorption and reflectivity measurements of bulk graphite and graphene paper are reported. In graphite, the relaxation of photoinduced electron–hole pairs happens through in-plane electron–electron and elec ...

Ultrafast excited-state dynamics of planar Pt, Pd, and Ni dithione-dithiolato complexes were investigated by transient absorption spectroscopy on the femtosecond-picosecond timescale. All studied complexes show a common photobehaviour, although individual ...

The ultrafast relaxation of aq. Fe(II)-tris(bipyridine) upon excitation into the singlet metal-to-ligand charge-transfer band (1MLCT) was characterized by femtosecond fluorescence up-conversion and transient absorption (TA) studies. The fluorescence expt. ...

Time-resolved fluorescence spectra from the RuN719 dye exhibit very short lifetimes (

We present a systematic study of the ultrafast fluorescence with broadband detection and similar to 110 fs resolution of 5,10,15,20-tetraphenylporphin (TPP) and 2,3,7,8,12,13,17,18-oc-taethylporphin (OEP), with open 3d-shell metals. We also revisit the cas ...

The fs-time-resolved study of a small UV dye in different solvents with fluorescence up-conversion and photon-echo techniques in the UV range provides new insight in cooling relaxation and solvation dynamics of non-polar molecules in polar solvents. ...

We compare UV transient grating (TG) experiments of aqueous tryptophan with transient absorption (TA) and fluorescence up-conversion measurements. The TG and TA signals show a bi-exponential rise with sub-ps and ps time constants, which are consistent with ...

The (sub)-ps relaxation processes in PbSe quantum dots of different sizes were measured by near-IR luminescence upconversion. The early-time spectra are characterized by emission from several low-lying excited states. The direct measurement of the Huang-Rh ...

We developed a fast multichannel detection system for pump-probe spectroscopy, capable of detecting single shot super-continuum spectra at the repetition rate (10-50 kHz) of an amplified femtosecond laser system. By tandem pumping the amplifier with three ...

Andrea Cannizzo

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Femtosecond Fluorescence and Intersystem Crossing in Rhenium(I) Carbonyl-Bipyridine Complexes

Charge migration and charge transfer in molecular systems

Coherent ultrafast torsional motion and isomerization of a biomimetic dipolar photoswitch

Real-time observation of the charge transfer to solvent dynamics

Origin of electronic absorption spectra of MLCT-excited and one-electron reduced 2,2 '-bipyridine and 1,10-phenanthroline complexes

Femtosecond UV Studies of the Electronic Relaxation Processes in Cytochrome c

A femtosecond fluorescence study of vibrational relaxation and cooling dynamics of UV dyes

Functional electric field changes in photoactivated proteins revealed by ultrafast Stark spectroscopy of the Trp residues

Ultrafast Excited-State Dynamics of Rhenium(I) Photosensitizers [Re(Cl)(CO)(3)(N,N)] and [Re(imidazole)(CO)(3)(N,N)](+): Diimine Effects

Energy transfer and relaxation mechanisms in Cytochrome c

Vibrational coherences and relaxation in the high-spin state of aqueous [Fell(bpy)3]2+

Femtosecond carrier dynamics in bulk graphite and graphene paper

Ultrafast electronic and vibrational relaxations in mixed-ligand dithione-dithiolato Ni, Pd, and Pt complexes

Ultrafast Nonadiabatic Dynamics of [FeII(bpy)3]2+ in Solution

Ultrafast fluorescence studies of dye sensitized solar cells

Ultrafast Broadband Fluorescence Up-conversion Study of the Electronic Relaxation of Metalloporphyrins

Broadband femtosecond fluorescence up-conversion and photon echo experiments in the UV

Ultraviolet transient absorption, transient grating and photon echo studies of aqueous tryptophan

Subpicosecond near-infrared fluorescence upconversion study of relaxation processes in PbSe quantum dots

Femtosecond pump/supercontinuum-probe setup with 20 kHz repetition rate