Lecture

Thermodynamics and Energetics I

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In course

ME-251: Thermodynamics and energetics I

The course introduces the basic concepts of thermodynamics and heat transfer, and thermodynamic properties of matter and their calculation. The students will master the concepts of heat, mass, and momentum conservation, and apply these concepts to thermody ...

Description

This lecture covers the fundamentals of thermodynamics and energetics, focusing on calculating internal energy, enthalpy, and entropy using equations of state and specific heat capacity. It also discusses the construction of thermodynamic tables and the use of Maxwell relations in deriving useful thermodynamic relations.

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Instructors (2)

Daniel Favrat

Daniel Favrat got his Master degree in Mechanical Engineering from EPFL in 1972 and his PhD also from EPFL. He then spent 12 years in industrial research laboratories in Canada (Esso Canada) and Switzerland (CERAC: Centre Européen de Recherche Atlas Copco). From 1988 to 2013, he was full professor and director of the Industrial Energy Systems Laboratory (LENI) at EPFL. During that period he was successively director of the Institute of Energy and director of the Institute of Mechanical Engineering. From August 2013 he works at EPFL Energy Center first as director ad interim and now as director technologies. His research fields include systemic analyses accounting for energy, environment and economics (so-called environomic optimisation) and advanced conversion systems for a more rational use of energy (heat pumps &ORC, engines, fuel cells, power plants, etc). He is a member of the Swiss Academy of Engineering Sciences and of the National Academy of Technology in France. He has also an active participation in the World Federation of Engineering Organizations (WFEO) as a member of the executive committee and vice-chair of the energy committee. He is associate editor of the journal "Energy" and of International Journal of thermodynamics. He is the author of several books on thermodynamics and energy systems analysis. He is also affiliate professor at the Royal Institute of Technology (KTH) in Stockholm.

Sophia Haussener

Sophia Haussener is an Associate Professor heading the Laboratory of Renewable Energy Science and Engineering at the Ecole Polytechnique Fédérale de Lausanne (EPFL). Her current research is focused on providing design guidelines for thermal, thermochemical, and photoelectrochemical energy conversion reactors through multi-physics modeling. Her research interests include: thermal sciences, fluid dynamics, charge transfer, electro-magnetism, and thermo/electro/photochemistry in complex multi-phase media on multiple scales. She received her MSc (2007) and PhD (2010) in Mechanical Engineering from ETH Zurich. Between 2011 and 2012, she was a postdoctoral researcher at the Joint Center of Artificial Photosynthesis (JCAP) and the Energy Environmental Technology Division of the Lawrence Berkeley National Laboratory (LBNL). She has published over 70 articles in peer-reviewed journals and conference proceedings. She has been awarded the ETH medal (2011), the Dimitris N. Chorafas Foundation award (2011), the ABB Forschungspreis (2012), the Prix Zonta (2015), the Global Change Award (2017), and the Raymond Viskanta Award (2019), and is a recipient of a Starting Grant of the Swiss National Science Foundation (2014). She is a deputy leader in the Swiss Competence Center for Energy Research (SCCER) on energy storage and acts as a Member of the Scientific Advisory Council of the Helmholtz Zentrum.

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Ontological neighbourhood

Physics

Thermodynamics: Statistical mechanics

Related concepts (32)

Thermodynamic equations

Thermodynamics is expressed by a mathematical framework of thermodynamic equations which relate various thermodynamic quantities and physical properties measured in a laboratory or production process. Thermodynamics is based on a fundamental set of postulates, that became the laws of thermodynamics. One of the fundamental thermodynamic equations is the description of thermodynamic work in analogy to mechanical work, or weight lifted through an elevation against gravity, as defined in 1824 by French physicist Sadi Carnot.

Thermodynamic temperature

Thermodynamic temperature is a quantity defined in thermodynamics as distinct from kinetic theory or statistical mechanics. Historically, thermodynamic temperature was defined by Lord Kelvin in terms of a macroscopic relation between thermodynamic work and heat transfer as defined in thermodynamics, but the kelvin was redefined by international agreement in 2019 in terms of phenomena that are now understood as manifestations of the kinetic energy of free motion of microscopic particles such as atoms, molecules, and electrons.

Maxwell relations

Maxwell's relations are a set of equations in thermodynamics which are derivable from the symmetry of second derivatives and from the definitions of the thermodynamic potentials. These relations are named for the nineteenth-century physicist James Clerk Maxwell. symmetry of second derivatives The structure of Maxwell relations is a statement of equality among the second derivatives for continuous functions. It follows directly from the fact that the order of differentiation of an analytic function of two variables is irrelevant (Schwarz theorem).

Internal energy

The internal energy of a thermodynamic system is the energy contained within it, measured as the quantity of energy necessary to bring the system from its standard internal state to its present internal state of interest, accounting for the gains and losses of energy due to changes in its internal state, including such quantities as magnetization. It excludes the kinetic energy of motion of the system as a whole and the potential energy of position of the system as a whole, with respect to its surroundings and external force fields.

Table of thermodynamic equations

Common thermodynamic equations and quantities in thermodynamics, using mathematical notation, are as follows: List of thermodynamic propertiesThermodynamic potentialFree entropy and Defining equation (physical chemistry) Many of the definitions below are also used in the thermodynamics of chemical reactions. Heat capacity and Thermal expansion Thermal conductivity The equations in this article are classified by subject. where kB is the Boltzmann constant, and Ω denotes the volume of macrostate in the phase space or otherwise called thermodynamic probability.

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