Lecture

Polymers: Structure and Properties

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In course

MSE-234: Mechanical behaviour of materials

Ce cours est une introduction au comportement mécanique, à l'élaboration, à la structure et au cycle de vie des grandes classes de matériaux de structure (métaux, polymères, céramiques et composites) ...

Description

This lecture covers the classification of polymers into thermoplastics, thermosets, and elastomers, discussing their molecular structures and properties. It delves into the concepts of polymerization, molecular weight, stereoisomerism, and crystalline structures. The lecture also explores the mechanical behavior of polymers under stress, deformation, and temperature variations, emphasizing the differences between thermoplastic and thermosetting polymers. Additionally, it explains the viscoelastic properties of polymers, including creep and relaxation tests, and the linear viscoelasticity model. The discussion extends to the influence of temperature on polymer behavior, activation energy, and the master curve concept for predicting material responses at different temperatures.

Instructors (3)

David Hernandez Escobar

Expertise Physical metallurgy, ceramics, micro-mechanical testing Education Ph.D. Materials Science and Engineering | 2016 – 2021 Michigan State University B.S. Materials Engineering | 2012 – 2016 Universidad Politécnica de Madrid

Julie Nathalie S Gheysen

Professionals experiences PhD student 2018–2022 Université Catholique de Louvain Teaching & PhD Courses Materials MSE-171 Introduction course of material science applied to usual building materials, especially concrete and metals. Description of their fabrication, mechanical and thermal properties and use in construction. Mechanical behaviour of materials MSE-234 This course provides an introduction to the mechanical behaviour, the processing, the structure and life-cycle o

Andreas Mortensen

Andreas Mortensen is currently Professor and Director of the Institute of Materials at the Swiss Federal Institute of Technology in Lausanne (EPFL), where he heads the Laboratory for Mechanical Metallurgy. He joined the faculty of EPFL 1997 after ten years, from 1986 to 1996, as a member of the faculty of the Department of Materials Science and Engineering at the Massachusetts Institute of Technology, where he held the successive titles of ALCOA Assistant Professor, Associate Professor, and Professor. His research is focussed on the processing, microstructural development and mechanical behavior of advanced metallic materials with particular focus on metal matrix composites and metal foams, on infiltration processing and capillarity, and on damage and fracture in metallic materials. He is author or co-author of two monographs, around one hundred and eighty scientific or technical publications and twelve patents. Born in San Francisco in 1957, of dual (Danish and US) nationality, Andreas Mortensen graduated in 1980 from the Ecole Nationale Supérieure des Mines de Paris with a Diplôme dIngénieur Civil, and earned his Ph.D. in the Department of Materials Science and Engineering at MIT in 1986. Besides his academic employment, he was a postdoctoral researcher at Nippon Steel during part of 1986, and was invited professor at the Ecole des Mines in Paris during the academic year 1995 to 1996. He is a member of the editorial committee of International Materials Reviews and has co-edited four books. He is a Fellow of ASM, a recipient of the Howe Medal and the Grossman Award of the American Society of Metals, was awarded the Péchiney Prize by the French Academy of Sciences and the Res Metallica Chair from the Katholieke Universiteit Leuven, received three EPFL teaching awards, is one of ISIs Highly Cited authors for Materials Science since 2002 and was awarded an ERC advanced grant in 2012.

Official source

Ontological neighbourhood

Chemistry

Organic chemistry: Polymer chemistry

Chemical engineering

Materials science: Deformation of materials

Related concepts (32)

Polymer

A polymer (ˈpɒlᵻmər; Greek poly-, "many" + -mer, "part") is a substance or material consisting of very large molecules called macromolecules, composed of many repeating subunits. Due to their broad spectrum of properties, both synthetic and natural polymers play essential and ubiquitous roles in everyday life. Polymers range from familiar synthetic plastics such as polystyrene to natural biopolymers such as DNA and proteins that are fundamental to biological structure and function.

Polymerization

In polymer chemistry, polymerization (American English), or polymerisation (British English), is a process of reacting monomer molecules together in a chemical reaction to form polymer chains or three-dimensional networks. There are many forms of polymerization and different systems exist to categorize them. In chemical compounds, polymerization can occur via a variety of reaction mechanisms that vary in complexity due to the functional groups present in the reactants and their inherent steric effects.

Thermosetting polymer

In materials science, a thermosetting polymer, often called a thermoset, is a polymer that is obtained by irreversibly hardening ("curing") a soft solid or viscous liquid prepolymer (resin). Curing is induced by heat or suitable radiation and may be promoted by high pressure, or mixing with a catalyst. Heat is not necessarily applied externally, but is often generated by the reaction of the resin with a curing agent (catalyst, hardener).

Viscoelasticity

In materials science and continuum mechanics, viscoelasticity is the property of materials that exhibit both viscous and elastic characteristics when undergoing deformation. Viscous materials, like water, resist shear flow and strain linearly with time when a stress is applied. Elastic materials strain when stretched and immediately return to their original state once the stress is removed. Viscoelastic materials have elements of both of these properties and, as such, exhibit time-dependent strain.

Thermoplastic elastomer

Thermoplastic elastomers (TPE), sometimes referred to as thermoplastic rubbers, are a class of copolymers or a physical mix of polymers (usually a plastic and a rubber) that consist of materials with both thermoplastic and elastomeric properties. While most elastomers are thermosets, thermoplastics are in contrast relatively easy to use in manufacturing, for example, by injection moulding. Thermoplastic elastomers show advantages typical of both rubbery materials and plastic materials.

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