Lecture

Clay Minerals: Structure and Properties

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In course

ENV-222: Soil sciences

Le cours est une introduction aux Sciences du sol. Il a pour but de présenter les principales caractéristiques, propriétés et fonctions des sols. Il fait appel à des notions théoriques mais également à des cas d'étude concrets à l'aide d'exercices et de tr ...

Description

This lecture covers the characteristics and properties of clay minerals, focusing on their structure, composition, and behavior in different environments. It explains the differences between mineralogical clays and granulometric clays, detailing their atomic arrangements and layer structures. The lecture also discusses the specific areas of clay minerals, their ability to change volume with humidity, and the adsorption of water molecules on their surfaces. Furthermore, it explores the origins of charges in clay minerals, including isomorphic substitutions and bond breaks, and their environmental consequences. The session concludes with a series of questions addressing the formation of organo-metallic complexes, mineralization processes, and the swelling power of montmorillonite.

Instructors (3)

David Andrew Barry

Research InterestsSubsurface hydrology, constructed wetlands, ecological engineering, in particular contaminant transport and remediation of soil and groundwater; more generally, models of hydrological and vadose zone processes; application of mathematical methods to hydrological processes; coastal zone sediment transport, aquifer-coastal ocean interactions; hydrodynamics and modelling of lakes.

Géraldine Michèle Bullinger

Teaching & PhD Courses Soil sciences ENV-222 This course is an introduction to Soil Sciences, and it focuses on the main soil characteristics, properties, and functions. The teaching is based on theoretical concepts, exercises as well as field and computer experiments.

Gabriele Manoli

Teaching & PhD PhD Students Yuxin Yin, Marc Duran Sala, Guo-Shiuan Lin Courses Adventure on Planet B PENS-231 This course will take students on a cosmic journey and then back to Earth to reflect on planetary challenges and their solutions. Climate and water sensitive urban design ENV-526 This project-based course introduces students to the field of urban climate and hydrology, with a focus on nature-based solutions for the design of climate and water resilient cities. Soi

Official source

Related concepts (15)

Mineral

In geology and mineralogy, a mineral or mineral species is, broadly speaking, a solid substance with a fairly well-defined chemical composition and a specific crystal structure that occurs naturally in pure form. The geological definition of mineral normally excludes compounds that occur only in living organisms. However, some minerals are often biogenic (such as calcite) or organic compounds in the sense of chemistry (such as mellite). Moreover, living organisms often synthesize inorganic minerals (such as hydroxylapatite) that also occur in rocks.

Adsorption

Adsorption is the adhesion of atoms, ions or molecules from a gas, liquid or dissolved solid to a surface. This process creates a film of the adsorbate on the surface of the adsorbent. This process differs from absorption, in which a fluid (the absorbate) is dissolved by or permeates a liquid or solid (the absorbent). Adsorption is a surface phenomenon and the adsorbate does not penetrate through the surface and into the bulk of the adsorbent, while absorption involves transfer of the absorbate into the volume of the material, although adsorption does often precede absorption.

Langmuir adsorption model

The Langmuir adsorption model explains adsorption by assuming an adsorbate behaves as an ideal gas at isothermal conditions. According to the model, adsorption and desorption are reversible processes. This model even explains the effect of pressure i.e. at these conditions the adsorbate's partial pressure, , is related to the volume of it, V, adsorbed onto a solid adsorbent. The adsorbent, as indicated in the figure, is assumed to be an ideal solid surface composed of a series of distinct sites capable of binding the adsorbate.

Specific surface area

Specific surface area (SSA) is a property of solids defined as the total surface area of a material per unit of mass, (with units of m2/kg or m2/g) or solid or bulk volume (units of m2/m3 or m−1). It is a physical value that can be used to determine the type and properties of a material (e.g. soil or snow). It has a particular importance for adsorption, heterogeneous catalysis, and reactions on surfaces. Values obtained for specific surface area depend on the method of measurement.

Clay

Clay is a type of fine-grained natural soil material containing clay minerals (hydrous aluminium phyllosilicates, e.g. kaolinite, Al2Si2O5(OH)4). Clays develop plasticity when wet but can be hardened through firing. Most pure clay minerals are white or light-coloured, but natural clays show a variety of colours from impurities, such as a reddish or brownish colour from small amounts of iron oxide. Clay is the oldest known ceramic material. Prehistoric humans discovered the useful properties of clay and used it for making pottery.

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