Lecture

Hydrogenation and Dehydrogenation of Pyridines and Quinolines

Graph Chat

Chat with Graph Search

Ask any question about EPFL courses, lectures, exercises, research, news, etc. or try the example questions below.

DISCLAIMER: The Graph Chatbot is not programmed to provide explicit or categorical answers to your questions. Rather, it transforms your questions into API requests that are distributed across the various IT services officially administered by EPFL. Its purpose is solely to collect and recommend relevant references to content that you can explore to help you answer your questions.

In course

CH-223: Organometallic chemistry

Basic organometallic chemistry will be covered in this course.

Structure and bonding in organometallic compounds.
reactivity of organometallic compounds, stoichiometric reactions, catalyzed reactions and reaction mechanisms. ...

Description

This lecture covers the hydrogenation and dehydrogenation of pyridines and quinolines, focusing on the catalysts, reaction conditions, and mechanistic considerations. The instructor discusses the importance of these reactions in organometallic chemistry, pharmaceutical applications, and energy storage, emphasizing the need for efficient methods to access key compounds. Control experiments, catalytic cycles, and potential applications in various industries are explored, highlighting the significance of understanding reaction mechanisms and optimizing catalyst performance. The lecture also touches on the use of DFT studies to complement experimental findings and the challenges of scaling up reactions. Overall, the lecture provides insights into the complex interplay between catalyst design, reaction conditions, and practical applications in the field of organometallic chemistry.

Instructors (2)

Felix Daniel Bobbink

Marinella Mazzanti

Expertise Inorganic Chemistry, Coordination ChemistryF-elements Chemistry Teaching & PhD Past EPFL PhD Students Julie Renée Michelle Andrez, Marta Falcone, Radmila Faizova, Davide Toniolo, Luciano Barluzzi, Aurélien René Willauer, Nadir Jori, Dieuwertje Katelijn Modder, Hsueh Fang-Che, Keerthi Shivaraam Rangaraj Ananthakumar, Mikhail Batov Past EPFL PhD Students as codirector Andreichenko Andrei Courses Chemistry of f elements CH-427 The course will provide a synopsis of the chemistry of f e

Official source

Related concepts (19)

Experiment

An experiment is a procedure carried out to support or refute a hypothesis, or determine the efficacy or likelihood of something previously untried. Experiments provide insight into cause-and-effect by demonstrating what outcome occurs when a particular factor is manipulated. Experiments vary greatly in goal and scale but always rely on repeatable procedure and logical analysis of the results. There also exist natural experimental studies.

Energy storage

Energy storage is the capture of energy produced at one time for use at a later time to reduce imbalances between energy demand and energy production. A device that stores energy is generally called an accumulator or battery. Energy comes in multiple forms including radiation, chemical, gravitational potential, electrical potential, electricity, elevated temperature, latent heat and kinetic. Energy storage involves converting energy from forms that are difficult to store to more conveniently or economically storable forms.

Design of experiments

The design of experiments (DOE or DOX), also known as experiment design or experimental design, is the design of any task that aims to describe and explain the variation of information under conditions that are hypothesized to reflect the variation. The term is generally associated with experiments in which the design introduces conditions that directly affect the variation, but may also refer to the design of quasi-experiments, in which natural conditions that influence the variation are selected for observation.

Scientific control

Informal improvements in any process or enquiry have been made by comparison between what was done previously and the new method for thousands of years. A scientific control is a modern formal experiment or observation designed to minimize the effects of variables other than the independent variable (i.e. confounding variables). This increases the reliability of the results, often through a comparison between control measurements and the other measurements. Scientific controls are a part of the scientific method.

Grid energy storage

Grid energy storage (also called large-scale energy storage) is a collection of methods used for energy storage on a large scale within an electrical power grid. Electrical energy is stored during times when electricity is plentiful and inexpensive (especially from intermittent power sources such as renewable electricity from wind power, tidal power and solar power) or when demand is low, and later returned to the grid when demand is high, and electricity prices tend to be higher.

Related lectures (42)

Energy Transition: Trends, Markets, and Challenges

Covers global energy challenges, the growth of renewables, energy security, unconventional fuels, and energy efficiency, highlighting the importance of renewable energy sources and energy storage applications.

Organometallic Reactions

Covers main organometallic reactions and factors driving them, with exercises predicting reaction products.

Chemical Kinetics: Reaction Rates

Explores the basics of chemical kinetics, emphasizing reaction rates and influencing factors.

Energy Storage Technologies: SMES, Superconductivity, and Lithium-Ion Batteries

Explores the significance of SMES systems, superconductivity, and lithium-ion batteries, highlighting their roles in energy storage and global sustainability.

Electrostatics: Capacitors and Energy Conversion