Lecture

Molecular Bonds: Quantum Physics and Chemical Interactions

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In course

PHYS-207(a): General physics : quanta

Ce cours est une introduction à la mécanique quantique. En partant de son développement historique, le cours traite les notions de complémentarité quantique et le principe d'incertitude, le processus de mesure, l'équation de Schrödinger, ainsi que des élém ...

Description

This lecture delves into the principles of quantum physics governing the electronic configuration of atoms, focusing on the rules of exclusion, Hund, and Aufbau. It explores the formation of molecular bonds, including covalent and ionic bonds, and the van der Waals interactions. The instructor explains the concepts of effective potential, electron affinity, and the mechanisms behind keesome, debye, and London interactions. The lecture also covers hydrogen bonding and its significance in DNA structure and protein folding. By the end, students will have a comprehensive understanding of the energy scales and strengths of various molecular bonds.

Instructor

Vincenzo Savona

Vincenzo Savona studied physics in Pisa at the Scuola Normale Superiore and the University of Pisa, prior to completing his PhD at the EPFL's Institute of Theoretical Physics. Subsequently he did post-doctoral work, first at the EPFL and then in the physics department of the Humboldt University of Berlin. In 2002, he returned to the EPFL to create his own research group, receiving a "professeur boursier" fellowship from the Swiss National Science Foundation. In 2006, he was appointed tenure-track assistant professor at the EPFL and joined the NCCR for Quantum Photonics. In 2010 he was appointed associate professor. Currently he directs the Laboratory of Theoretical Physics of Nanosystems.

Official source

Related concepts (32)

Chemical bond

A chemical bond is a lasting attraction between atoms or ions that enables the formation of molecules, crystals, and other structures. The bond may result from the electrostatic force between oppositely charged ions as in ionic bonds, or through the sharing of electrons as in covalent bonds. The strength of chemical bonds varies considerably; there are "strong bonds" or "primary bonds" such as covalent, ionic and metallic bonds, and "weak bonds" or "secondary bonds" such as dipole–dipole interactions, the London dispersion force, and hydrogen bonding.

Hydrogen bond

In chemistry, a hydrogen bond (or H-bond) is a primarily electrostatic force of attraction between a hydrogen (H) atom which is covalently bound to a more electronegative "donor" atom or group (Dn), and another electronegative atom bearing a lone pair of electrons—the hydrogen bond acceptor (Ac). Such an interacting system is generally denoted , where the solid line denotes a polar covalent bond, and the dotted or dashed line indicates the hydrogen bond.

Covalent bond

A covalent bond is a chemical bond that involves the sharing of electrons to form electron pairs between atoms. These electron pairs are known as shared pairs or bonding pairs. The stable balance of attractive and repulsive forces between atoms, when they share electrons, is known as covalent bonding. For many molecules, the sharing of electrons allows each atom to attain the equivalent of a full valence shell, corresponding to a stable electronic configuration. In organic chemistry, covalent bonding is much more common than ionic bonding.

Ionic bonding

Ionic bonding is a type of chemical bonding that involves the electrostatic attraction between oppositely charged ions, or between two atoms with sharply different electronegativities, and is the primary interaction occurring in ionic compounds. It is one of the main types of bonding, along with covalent bonding and metallic bonding. Ions are atoms (or groups of atoms) with an electrostatic charge. Atoms that gain electrons make negatively charged ions (called anions). Atoms that lose electrons make positively charged ions (called cations).

Coordinate covalent bond

In coordination chemistry, a coordinate covalent bond, also known as a dative bond, dipolar bond, or coordinate bond is a kind of two-center, two-electron covalent bond in which the two electrons derive from the same atom. The bonding of metal ions to ligands involves this kind of interaction. This type of interaction is central to Lewis acid–base theory. Coordinate bonds are commonly found in coordination compounds. Coordinate covalent bonding is ubiquitous.

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