Lecture

Nanocrystal Properties: Size and Shape Control

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In course

ChE-430: Nanomaterials for chemical engineering application

This course provides an overview on nanoparticle synthesis and their use in different energy-related applications. The first part of the course is more fundamental and chemistry oriented. The second part is more applied and chemical engineering oriented. T ...

Description

This lecture by the instructor covers the importance of monodispersity and homogeneous composition in controlling nanocrystal properties. Topics include burst and delayed nucleation techniques, continuous monomer supply for size tuning, and the influence of factors like temperature, ligand steric hindrance, and chemical potential on size and shape control. The lecture also delves into the Wulff construction, ligand effects on surface energy, and the impact of seed crystalline phase symmetry on final nanocrystal shape.

Instructor

Raffaella Buonsanti

Teaching & PhD PhD Students Riya Gupta, Jennifer Calderon Mora, Coline Boulanger, Moritz Tritschler, Marco Fabbiano, Seyedmohamadjavad Chabok, Hugh Andrew Warkentin Past EPFL PhD Students Chethana Janardhana Gadiyar, Seryio Saris, Valeria Mantella, Seyedehbehnaz Varandili, Pranit Srinivas Iyengar, Yannick Thomas Guntern, Jan Vávra, Laia Castilla Amorós, Valery Okatenko, Ona Segura Lecina, Ludovic Emile Frédy Zaza, Petru Pasquale Albertini Courses Introduction to chemical engineering Laboratory Works

Official source

Ontological neighbourhood

Physics

Thermodynamics: Statistical mechanics

Related concepts (32)

Thermodynamic process

Classical thermodynamics considers three main kinds of thermodynamic process: (1) changes in a system, (2) cycles in a system, and (3) flow processes. (1)A Thermodynamic process is a process in which the thermodynamic state of a system is changed. A change in a system is defined by a passage from an initial to a final state of thermodynamic equilibrium. In classical thermodynamics, the actual course of the process is not the primary concern, and often is ignored.

Thermodynamic equilibrium

Thermodynamic equilibrium is an axiomatic concept of thermodynamics. It is an internal state of a single thermodynamic system, or a relation between several thermodynamic systems connected by more or less permeable or impermeable walls. In thermodynamic equilibrium, there are no net macroscopic flows of matter nor of energy within a system or between systems. In a system that is in its own state of internal thermodynamic equilibrium, no macroscopic change occurs.

Thermodynamic cycle

A thermodynamic cycle consists of linked sequences of thermodynamic processes that involve transfer of heat and work into and out of the system, while varying pressure, temperature, and other state variables within the system, and that eventually returns the system to its initial state. In the process of passing through a cycle, the working fluid (system) may convert heat from a warm source into useful work, and dispose of the remaining heat to a cold sink, thereby acting as a heat engine.

Chemical potential

In thermodynamics, the chemical potential of a species is the energy that can be absorbed or released due to a change of the particle number of the given species, e.g. in a chemical reaction or phase transition. The chemical potential of a species in a mixture is defined as the rate of change of free energy of a thermodynamic system with respect to the change in the number of atoms or molecules of the species that are added to the system.

Thermodynamic temperature

Thermodynamic temperature is a quantity defined in thermodynamics as distinct from kinetic theory or statistical mechanics. Historically, thermodynamic temperature was defined by Lord Kelvin in terms of a macroscopic relation between thermodynamic work and heat transfer as defined in thermodynamics, but the kelvin was redefined by international agreement in 2019 in terms of phenomena that are now understood as manifestations of the kinetic energy of free motion of microscopic particles such as atoms, molecules, and electrons.

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