Lecture

Reaction Kinetics in Cement Hydration

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In course

MSE-171: Materials

Une introduction à la science des matériaux appliquée aux matériaux de construction courants, en particulier le béton et les métaux. Description de leur fabrication, leurs comportements mécanique et thermique et leur utilisation en construction. ...

Description

This lecture covers the reaction kinetics in cement hydration, focusing on the dominant reactions of c3s, the heat of hydration, and the impact of additives and temperature on the reaction rate. It also discusses the importance of gypsum in controlling the reaction of c3a and the essential hydration products for concrete strength development.

Instructors (6)

Cyril Henri Dénéréaz

Karen Scrivener

De nationalité anglaise, Karen Scrivener est née en 1958. Au cours de sa carrière, ses travaux et sa recherche traitaient des domaines suivants: Identification du développement microstucturale pendant l'hydratation du ciment. Elaboration d'une approche multitechnique pour étudier la microstucture des ciments et bétons, avec accent sur la quantification par analyse des images d'électrons retrodiffusés. Caractérisation de l'auréole de transition de la pâte de ciment autour des granulats. Compréhension des processus de dégardation des bétons, en particulier le gonflement lié à la formation de l'éttringite retardée dans les bétons étuvés.

Lionel Sofia

Emmanuelle Anne Boehm Courjault

Teaching & PhD Past EPFL PhD Students as codirector Solène Anne-Lise Albinski Courses Building materials + Laboratory work MSE-322 Materials science of common non metallic building materials, with emphasis on cementitious materials (concrete). Chemical composition, fabrication and behaviour in service Materials MSE-171 Introduction course of material science applied to usual building materials, especially concrete and metals. Description of their fabrication, mechanical and

Julie Nathalie S Gheysen

Professionals experiences PhD student 2018–2022 Université Catholique de Louvain Teaching & PhD Courses Materials MSE-171 Introduction course of material science applied to usual building materials, especially concrete and metals. Description of their fabrication, mechanical and thermal properties and use in construction. Mechanical behaviour of materials MSE-234 This course provides an introduction to the mechanical behaviour, the processing, the structure and life-cycle o

Jean-Marie Drezet

1992-1996: PhD work at Laboratoire de Métallurgie Physique under the supervision of Prof. Michel Rappaz (cf : http://library.epfl.ch/theses/?display=detail&nr=1509) 1997-2000: EMPACT project (European Modelling Programme for Aluminium Casting Technologies) 2001-2004: VIRCAST project (European Virtual Casting) 2005-2006: Study of the sawing process of rolling sheet al. ingots (Alcan Fonds) 2005-2006: WelAIR project (Welding of Airframes, EADS) 2005-2008: study of the electron beam welding of Cu-Cr-Zr alloys (CEA, France) 2006-2008: study of the laser beam welding of Al-Li alloys (EADS, France) 2008-2011: co-supervision with Prof. A. Nussbaumer of the PhD work of C. Acevedo on the influence of residual stresses on the fatigue design of tubular welded joints, http://library.epfl.ch/theses/?nr=5056 2007-2010: co-supervision with Prof. J.-F. Molinari of the PhD work of K. Shahim on the Normal Pressure Hydrocephalus (S. Momjian, HU-Genève et R. Sinkus, ESPCI-Paris), http://library.epfl.ch/theses/?nr=5191 2008-2012: co-supervision with Prof. M. Rappaz of the PhD work of M. Sistaninia on the simulation of solidification cracking using granular models (CCMX-MERU project) 2010-2014: supervision with Prof. M. Rappaz of the PhD work of N. Chobaut on the modelling of stresses during quenching of thick heat treatable aluminium parts (CCMX-MERU project) 2011-2015: supervision with Prof. H. Van Swygenhoven-Moens of the PhD work of P. Schloth on precipitation during quenching of thick heat treatable aluminium parts (CCMX-MERU project)

Official source

Related concepts (22)

Cement

A cement is a binder, a chemical substance used for construction that sets, hardens, and adheres to other materials to bind them together. Cement is seldom used on its own, but rather to bind sand and gravel (aggregate) together. Cement mixed with fine aggregate produces mortar for masonry, or with sand and gravel, produces concrete. Concrete is the most widely used material in existence and is behind only water as the planet's most-consumed resource.

Reinforced concrete

Reinforced concrete, also called ferroconcrete, is a composite material in which concrete's relatively low tensile strength and ductility are compensated for by the inclusion of reinforcement having higher tensile strength or ductility. The reinforcement is usually, though not necessarily, steel bars (rebar) and is usually embedded passively in the concrete before the concrete sets. However, post-tensioning is also employed as a technique to reinforce the concrete. In terms of volume used annually, it is one of the most common engineering materials.

Cement clinker

Cement clinker is a solid material produced in the manufacture of Portland cement as an intermediary product. Clinker occurs as lumps or nodules, usually to in diameter. It is produced by sintering (fusing together without melting to the point of liquefaction) limestone and aluminosilicate materials such as clay during the cement kiln stage. The Portland clinker essentially consists of four minerals: two calcium silicates, alite (Ca3SiO5) and belite (Ca2SiO4), along with tricalcium aluminate (Ca3Al2O6) and calcium aluminoferrite (Ca2(Al,Fe)2O5).

Portland cement

Portland cement is the most common type of cement in general use around the world as a basic ingredient of concrete, mortar, stucco, and non-specialty grout. It was developed from other types of hydraulic lime in England in the early 19th century by Joseph Aspdin, and is usually made from limestone. It is a fine powder, produced by heating limestone and clay minerals in a kiln to form clinker, grinding the clinker, and adding 2 to 3 percent of gypsum. Several types of portland cement are available.

Mineral hydration

In inorganic chemistry, mineral hydration is a reaction which adds water to the crystal structure of a mineral, usually creating a new mineral, commonly called a hydrate. In geological terms, the process of mineral hydration is known as retrograde alteration and is a process occurring in retrograde metamorphism. It commonly accompanies metasomatism and is often a feature of wall rock alteration around ore bodies. Hydration of minerals occurs generally in concert with hydrothermal circulation which may be driven by tectonic or igneous activity.

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