Lecture

Quantum Principles: Atoms and Molecules

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In course

MICRO-312: Physics of semiconductors devices

Les étudiants savent expliquer la physique des composants semiconducteurs, tels que diodes, transistors et composants MOS. Ils les utilisent dans des circuits électroniques fondamentaux tels qu'inverseurs et ampli. ...

Description

This lecture discusses the application of quantum principles to atoms and molecules, focusing on the dual nature of electrons as both particles and waves. It begins by revisiting previous concepts, emphasizing the characteristics of particles and waves, including energy and momentum. The instructor explains stationary waves using models like a guitar string and explores the energy levels of electrons in atoms, highlighting discrete energy states. The lecture further delves into atomic orbitals, particularly for hydrogen, and the concept of hybridization when two atoms approach each other. The formation of stable molecules, such as H2, is analyzed, contrasting it with unstable configurations like He2. The discussion extends to multi-dimensional chains and networks, illustrating how atoms bond to form complex structures. The instructor concludes by summarizing the conditions necessary for stable molecular formation and the implications of quantum mechanics in understanding atomic interactions.

Instructor

Pierre-André Besse

Teaching & PhD Past EPFL PhD Students Klaus Ehrmann Courses La science quantique : une vision singulière MICRO-444 Students understand the characteristics of quantum science. They master the formalism and use it in basic quantum systems: quantum wells, wires, dots or qubits. Physics of semiconductors devices MICRO-312 The students are able to explain the physics of semiconductor devices like diodes, transistors, and MOS devices. They use such devices in fundamental electroni

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Related concepts (32)

Molecular orbital theory

In chemistry, molecular orbital theory (MO theory or MOT) is a method for describing the electronic structure of molecules using quantum mechanics. It was proposed early in the 20th century. In molecular orbital theory, electrons in a molecule are not assigned to individual chemical bonds between atoms, but are treated as moving under the influence of the atomic nuclei in the whole molecule. Quantum mechanics describes the spatial and energetic properties of electrons as molecular orbitals that surround two or more atoms in a molecule and contain valence electrons between atoms.

Orbital hybridisation

In chemistry, orbital hybridisation (or hybridization) is the concept of mixing atomic orbitals to form new hybrid orbitals (with different energies, shapes, etc., than the component atomic orbitals) suitable for the pairing of electrons to form chemical bonds in valence bond theory. For example, in a carbon atom which forms four single bonds the valence-shell s orbital combines with three valence-shell p orbitals to form four equivalent sp3 mixtures in a tetrahedral arrangement around the carbon to bond to four different atoms.

Quantum mechanics

Quantum mechanics is a fundamental theory in physics that provides a description of the physical properties of nature at the scale of atoms and subatomic particles. It is the foundation of all quantum physics including quantum chemistry, quantum field theory, quantum technology, and quantum information science. Classical physics, the collection of theories that existed before the advent of quantum mechanics, describes many aspects of nature at an ordinary (macroscopic) scale, but is not sufficient for describing them at small (atomic and subatomic) scales.

Energy level

A quantum mechanical system or particle that is bound—that is, confined spatially—can only take on certain discrete values of energy, called energy levels. This contrasts with classical particles, which can have any amount of energy. The term is commonly used for the energy levels of the electrons in atoms, ions, or molecules, which are bound by the electric field of the nucleus, but can also refer to energy levels of nuclei or vibrational or rotational energy levels in molecules.

Atomic orbital

In atomic theory and quantum mechanics, an atomic orbital (ˈɔːrbɪtəl) is a function describing the location and wave-like behavior of an electron in an atom. This function can be used to calculate the probability of finding any electron of an atom in any specific region around the atom's nucleus. The term atomic orbital may also refer to the physical region or space where the electron can be calculated to be present, as predicted by the particular mathematical form of the orbital.

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