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Lecture

Dynamics & Kinetics: Center of Mass and Reactive Hard Spheres

In course

CH-310: Dynamics and kinetics

The course covers the principles of chemical kinetics, including differential rate laws, derivation of exact and approximate integral rate laws for common elementary and composite reactions, fundamentals of collision and transition state theories, and appl ...

Description

This lecture covers the concept of center of mass, coordinates, and the conservation of momentum, followed by an in-depth analysis of reactive hard spheres, collision rates, and the Arrhenius equation in the context of kinetics.

Instructor

Ulrich Lorenz

Official source

Related concepts (32)

Center-of-momentum frame

In physics, the center-of-momentum frame (COM frame), also known as zero-momentum frame, is the inertial frame in which the total momentum of the system vanishes. It is unique up to velocity, but not origin. The center of momentum of a system is not a location, but a collection of relative momenta/velocities: a reference frame. Thus "center of momentum" is a short for "center-of-momentum ". A special case of the center-of-momentum frame is the center-of-mass frame: an inertial frame in which the center of mass (which is a single point) remains at the origin.

Momentum

In Newtonian mechanics, momentum (: momenta or momentums; more specifically linear momentum or translational momentum) is the product of the mass and velocity of an object. It is a vector quantity, possessing a magnitude and a direction. If m is an object's mass and v is its velocity (also a vector quantity), then the object's momentum p (from Latin pellere "push, drive") is: In the International System of Units (SI), the unit of measurement of momentum is the kilogram metre per second (kg⋅m/s), which is equivalent to the newton-second.

Angular momentum

In physics, angular momentum (sometimes called moment of momentum or rotational momentum) is the rotational analog of linear momentum. It is an important physical quantity because it is a conserved quantity – the total angular momentum of a closed system remains constant. Angular momentum has both a direction and a magnitude, and both are conserved. Bicycles and motorcycles, flying discs, rifled bullets, and gyroscopes owe their useful properties to conservation of angular momentum.

Conservation law

In physics, a conservation law states that a particular measurable property of an isolated physical system does not change as the system evolves over time. Exact conservation laws include conservation of mass-energy, conservation of linear momentum, conservation of angular momentum, and conservation of electric charge. There are also many approximate conservation laws, which apply to such quantities as mass, parity, lepton number, baryon number, strangeness, hypercharge, etc.

Arrhenius equation

In physical chemistry, the Arrhenius equation is a formula for the temperature dependence of reaction rates. The equation was proposed by Svante Arrhenius in 1889, based on the work of Dutch chemist Jacobus Henricus van 't Hoff who had noted in 1884 that the van 't Hoff equation for the temperature dependence of equilibrium constants suggests such a formula for the rates of both forward and reverse reactions. This equation has a vast and important application in determining the rate of chemical reactions and for calculation of energy of activation.

Related lectures (39)

Plasma Collisions: Coulomb Force

Analyzes Coulomb collisions between charged particles and the conservation of energy, momentum, and angular momentum.

Collision Kinetics: Theory and Applications

Covers the theory and applications of collision kinetics in understanding molecular interactions.

Basic Concepts of Kinetics: Reactions and Rate Constants

Covers the basic concepts of kinetics, including reaction mechanisms and rate laws.

Center of Mass Coordinates

Discusses center of mass coordinates, collision rates, effusion, and molecule behavior.

Reactive Hard Spheres Model