Lecture

Phase Transformations II: solid-state transformations

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In course

PHYS-307: Physics of materials

This course discusses materials physics associated with the mechanical and structural properties of solids, primarily focusing on the physics of dislocation defect dynamics and linking diffusion kinetics to the fundamental physics of phase transformations. ...

Description

This lecture covers solid-state transformations, focusing on nucleation, solidification, and heterogeneous nucleation. It also discusses nucleation statistics, precipitation sequences, and the kinetics of transformation using the Johnson-Mehl-Avrami-Kolmogrov equation. The presentation delves into nucleation rates, nucleation at grain boundaries, and the derivation of the JMAK equation. Additionally, it explores hardness testing techniques, the correlation between hardness and yield stress, and transformations without diffusion. The lecture concludes with a study of thermodynamics, hysteresis, shape memory effects, and pseudo-elasticity in materials like CuZnSn.

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Instructor

Thomas La Grange

Expertise Electron Microscopy, Aberration Correct Scanning Transmission Electron Microscopy, Electron Diffraction, Ultrafast Transmission Electron Microscopy, Electron Energy Loss Spectroscopy, Energy Dispersive Spectroscopy, Materials Science, High-speed deformation, Dislocation Dynamics, Skyrmionics, Martensitic Phase Transformation Theory, Solidification Expertise Electron Microscopy, Aberration Correct Scanning Transmission Electron Microscopy, Electron Diffraction, Ultrafast Transmission Electron Micro

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Related concepts (32)

Nucleation

In thermodynamics, nucleation is the first step in the formation of either a new thermodynamic phase or structure via self-assembly or self-organization within a substance or mixture. Nucleation is typically defined to be the process that determines how long an observer has to wait before the new phase or self-organized structure appears. For example, if a volume of water is cooled (at atmospheric pressure) below 0 °C, it will tend to freeze into ice, but volumes of water cooled only a few degrees below 0 °C often stay completely free of ice for long periods (supercooling).

Thermodynamics

Thermodynamics is a branch of physics that deals with heat, work, and temperature, and their relation to energy, entropy, and the physical properties of matter and radiation. The behavior of these quantities is governed by the four laws of thermodynamics which convey a quantitative description using measurable macroscopic physical quantities, but may be explained in terms of microscopic constituents by statistical mechanics.

Laws of thermodynamics

The laws of thermodynamics are a set of scientific laws which define a group of physical quantities, such as temperature, energy, and entropy, that characterize thermodynamic systems in thermodynamic equilibrium. The laws also use various parameters for thermodynamic processes, such as thermodynamic work and heat, and establish relationships between them. They state empirical facts that form a basis of precluding the possibility of certain phenomena, such as perpetual motion.

Diffusionless transformation

Diffusionless transformations, also referred to as displacive transformations, are solid-state changes in the crystal structure that do not rely on the diffusion of atoms over long distances. Instead, they occur due to coordinated shifts in atomic positions, where atoms move by a distance less than the span between neighboring atoms while maintaining their relative arrangement. An illustrative instance of this is the martensitic transformation observed in steel.

Chemical thermodynamics

Chemical thermodynamics is the study of the interrelation of heat and work with chemical reactions or with physical changes of state within the confines of the laws of thermodynamics. Chemical thermodynamics involves not only laboratory measurements of various thermodynamic properties, but also the application of mathematical methods to the study of chemical questions and the spontaneity of processes. The structure of chemical thermodynamics is based on the first two laws of thermodynamics.

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