Lecture

Van der Waals Gas

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In course

PHYS-105: Advanced physics II (thermodynamics)

Ce cours présente la thermodynamique en tant que théorie permettant une description d'un grand nombre de phénomènes importants en physique, chimie et ingéniere, et d'effets de transport. Une introduction à la physique statistique renforce les notions acqu ...

Description

This lecture covers the definition of van der Waals gas, experiments, attraction and repulsion between molecules, molar volume, critical values, and the construction of Maxwell. It also explains the reduced form of the equation of state.

Instructors (2)

Jean-Philippe Ansermet

Jean-Philippe Ansermet was born March 1, 1957 in Lausanne (legal origin Vaumarcus, NE). He obtained a diploma as physics engineer of EPFL in 1980. He went on to get a PhD from the University of Illinois at Urbana-Champaign where, from 1985 to 1987, he persued as post-doc with Prof. Slichter his research on catalysis by solid state NMR studies of molecules bound to the surface of catalysts. From 1987 to 1992 he worked at the materials research center of Ciba-Geigy, on polymers for microelectronics, composites, dielectrics and organic charge transfer complexes. In March 1992, as professor of experimental physics, he developed a laboratory on the theme of nanostructured materials and turned full professor in 1995. Since 1992, he teaches classical mechanics, first to future engineering students, since 2004 to physics majors. Since 2000, he teaches thermodynamics also, to the same group of students. He offers a graduate course in spintronics, and another on spin dynamics. His research activities concern the fabrication and properties of magnetic nanostructures produced by electrodeposition. His involvement since the early days of spintronics have allowed him to gain recognition for his work on giant magnetoresistance (CPP-GMR), magnetic relaxation of single nanostructures, and was among the leading groups demonstrating magnetization reversal by spin-polarized currents. Furthermore, his group uses nuclear magnetic resonance , on the one hand as means of investigation of surfaces and electrodes, on the other hand, as a local probe of the electronic properties of complex ferromagnetic oxides.

Cécile Hébert

Cécile Hébert was born in France in 1970. She obtained her Ingeneer degree (physics) and her PhD degree (design of a new energy filter for transmission electron microscopy, under the direction of Prof. B. Jouffrey) at the Ecole Centrale in Paris. As a post doc with Prof. P. Schattschneider, she was working on the calculation of the fine structure of ionisation edges in EELS. As a research assistant at the Vienna University of Technology, she was one of the main participant to the CHIRALTEM project dealing with the measurement of magnetic circular dichroism in the electron microscope.

Official source

Related concepts (12)

Molar volume

In chemistry and related fields, the molar volume, symbol Vm, or of a substance is the ratio of the volume occupied by a substance to the amount of substance, usually given at a given temperature and pressure. It is equal to the molar mass (M) divided by the mass density (ρ): The molar volume has the SI unit of cubic metres per mole (m3/mol), although it is more typical to use the units cubic decimetres per mole (dm3/mol) for gases, and cubic centimetres per mole (cm3/mol) for liquids and solids.

Equation of state

In physics and chemistry, an equation of state is a thermodynamic equation relating state variables, which describe the state of matter under a given set of physical conditions, such as pressure, volume, temperature, or internal energy. Most modern equations of state are formulated in the Helmholtz free energy. Equations of state are useful in describing the properties of pure substances and mixtures in liquids, gases, and solid states as well as the state of matter in the interior of stars.

Amount of substance

In chemistry, the amount of substance (symbol n) in a given sample of matter is defined as a ratio (n = N/NA) between the number of elementary entities (N) and the Avogadro constant (NA). The entities are usually molecules, atoms, or ions of a specified kind. The particular substance sampled may be specified using a subscript, e.g., the amount of sodium chloride (NaCl) would be denoted as nNaCl. The unit of amount of substance in the International System of Units is the mole (symbol: mol), a base unit.

Volume (thermodynamics)

In thermodynamics, the volume of a system is an important extensive parameter for describing its thermodynamic state. The specific volume, an intensive property, is the system's volume per unit of mass. Volume is a function of state and is interdependent with other thermodynamic properties such as pressure and temperature. For example, volume is related to the pressure and temperature of an ideal gas by the ideal gas law. The physical volume of a system may or may not coincide with a control volume used to analyze the system.

Molar heat capacity

The molar heat capacity of a chemical substance is the amount of energy that must be added, in the form of heat, to one mole of the substance in order to cause an increase of one unit in its temperature. Alternatively, it is the heat capacity of a sample of the substance divided by the amount of substance of the sample; or also the specific heat capacity of the substance times its molar mass. The SI unit of molar heat capacity is joule per kelvin per mole, J⋅K−1⋅mol−1.

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