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Lecture

Variational Principle: Quantum Physics II

In course

PHYS-314: Quantum physics II

The aim of this course is to familiarize the student with the concepts, methods and consequences of quantum physics. ...

Description

This lecture introduces the variational principle in quantum physics, focusing on the ground state energy and excited states. The instructor explains how to use this principle to approximate energy levels and find the fundamental state of a system.

Instructors (3)

Zoë Holmes

Vincenzo Savona

Vincenzo Savona studied physics in Pisa at the Scuola Normale Superiore and the University of Pisa, prior to completing his PhD at the EPFL's Institute of Theoretical Physics. Subsequently he did post-doctoral work, first at the EPFL and then in the physics department of the Humboldt University of Berlin. In 2002, he returned to the EPFL to create his own research group, receiving a "professeur boursier" fellowship from the Swiss National Science Foundation. In 2006, he was appointed tenure-track assistant professor at the EPFL and joined the NCCR for Quantum Photonics. In 2010 he was appointed associate professor. Currently he directs the Laboratory of Theoretical Physics of Nanosystems.

Florent Gérard Krzakala

Official source

Related concepts (32)

Quantum computing

A quantum computer is a computer that exploits quantum mechanical phenomena. At small scales, physical matter exhibits properties of both particles and waves, and quantum computing leverages this behavior, specifically quantum superposition and entanglement, using specialized hardware that supports the preparation and manipulation of quantum states. Classical physics cannot explain the operation of these quantum devices, and a scalable quantum computer could perform some calculations exponentially faster than any modern "classical" computer.

Excited state

In quantum mechanics, an excited state of a system (such as an atom, molecule or nucleus) is any quantum state of the system that has a higher energy than the ground state (that is, more energy than the absolute minimum). Excitation refers to an increase in energy level above a chosen starting point, usually the ground state, but sometimes an already excited state. The temperature of a group of particles is indicative of the level of excitation (with the notable exception of systems that exhibit negative temperature).

Quantum mechanics

Quantum mechanics is a fundamental theory in physics that provides a description of the physical properties of nature at the scale of atoms and subatomic particles. It is the foundation of all quantum physics including quantum chemistry, quantum field theory, quantum technology, and quantum information science. Classical physics, the collection of theories that existed before the advent of quantum mechanics, describes many aspects of nature at an ordinary (macroscopic) scale, but is not sufficient for describing them at small (atomic and subatomic) scales.

Ground state

The ground state of a quantum-mechanical system is its stationary state of lowest energy; the energy of the ground state is known as the zero-point energy of the system. An excited state is any state with energy greater than the ground state. In quantum field theory, the ground state is usually called the vacuum state or the vacuum. If more than one ground state exists, they are said to be degenerate. Many systems have degenerate ground states.

Variational principle

In science and especially in mathematical studies, a variational principle is one that enables a problem to be solved using calculus of variations, which concerns finding functions that optimize the values of quantities that depend on those functions. For example, the problem of determining the shape of a hanging chain suspended at both ends—a catenary—can be solved using variational calculus, and in this case, the variational principle is the following: The solution is a function that minimizes the gravitational potential energy of the chain.

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