Lecture

Phase Diagrams: Constituents and Phases

Graph Chat

Chat with Graph Search

Ask any question about EPFL courses, lectures, exercises, research, news, etc. or try the example questions below.

DISCLAIMER: The Graph Chatbot is not programmed to provide explicit or categorical answers to your questions. Rather, it transforms your questions into API requests that are distributed across the various IT services officially administered by EPFL. Its purpose is solely to collect and recommend relevant references to content that you can explore to help you answer your questions.

In course

MSE-101(b): Materials:from chemistry to properties

Ce cours permet l'acquisition des notions essentielles relatives à la structure de la matière, aux équilibres et à la réactivité chimique en liaison avec les propriétés mécaniques, thermiques, électriques, magnétiques et optiques des matériaux. ...

Description

This lecture covers the concept of phase diagrams in materials science, focusing on binary and unary systems. It explains the relationship between temperature, composition, and the phases present in a system. The lecture also delves into the calculation of molar and mass compositions, the Gibbs phase rule, and the enthalpy of state changes. Additionally, it discusses the characteristics of diffusion in materials and the activation energy involved. The instructor provides insights into the behavior of different phases in unary systems and the energy transformations during state changes.

This video is available exclusively on Mediaspace for a restricted audience. Please log in to MediaSpace to access it if you have the necessary permissions.

Watch on Mediaspace

Instructors (4)

Roland Logé

Roland Logé is an associate professor at EPFL, with a primary affiliation to the Materials Institute, and a secondary affiliation to the Microengineering Institute. After graduating in 1994 at UCL (Belgium) in Materials Engineering, he earned a Master of Science in Mechanics in 1995, at UCSB Santa Barbara (USA). He received his PhD at Mines Paristech-CEMEF (France) in 1999, where he specialized in metal forming and associated microstructure evolutions. After a postdoc at Cornell University (USA) between 1999 and 2001, he entered CNRS in France. In 2008, he was awarded the ALCAN prize from the French Academy of Sciences, together with Yvan Chastel. In 2009 he became head of the Metallurgy-Structure-Rheology research group at CEMEF. In 2011, he launched a “Groupement de Recherche” (GDR), funded by CNRS, networking most of the researchers in France involved in recrystallization and grain growth. In 2013, he became Research Director at CNRS. In March 2014 he joined EPFL as the head of the Laboratory of Thermomechanical Metallurgy.

Michel Rappaz

After a PhD in solid state physics (1978) at the Ecole Polytechnique Fédérale de Lausanne (EPFL) and a post-doc at Oak Ridge National Laboratory, Michel Rappaz joined the Institute of Materials of EPFL in 1981. After two years in an engineering company, he came back to EPFL in 1984 where he was nominated Adjunct Professor in 1990 and Full Professor in 2003. He retired from EPFL in 2015 and is now Emeritus Professor and independent consultant for several industries and research centres. His main interests are in phase transformations and solidification, in particular the coupling of macroscopic aspects of heat and mass transfer with microscopic aspects of microstructure and defect formation. Among his diverse achievements, one can mention in particular the development of cellular automata for grain structure predictions and of granular models for hot tearing formation in castings, the coupling of Finite Element method with microscopic models of nucleation and growth, the application of the phase field method to the understanding of various microstructures, the discovery of quasicrystal mediated-nucleation in alloys, and many other studies both fundamental at the microstructure-defect level and more applied at the level of processes. Some of the software developments have been commercialized by a spin-off company founded by his group in 1991 (Calcom SA), now part of the French company ESI. Michel Rappaz initiated in 1992 an annual postgraduate course on solidification which has been attended by more than 900 participants from all over the world. He is presently collaborating closely with another spin-off company started from his group, Novamet SàrL. Michel Rappaz has received several awards, in particular the Mathewson co-author award (1994) and author award (1997) of the American Mineral, Metals and Materials Society (TMS), the Koerber foundation award jointly with Profs Y. Bréchet and M. Asbby (1996), the Sainte-Claire Deville Medal (1996) and the Grand Medal (2011) from the French Materials Society, the Bruce Chalmers Award of TMS (2002), the Mc Donald Memorial Lecture award of Canada (2005), the FEMS European Materials Gold Medal (2013) and the Brimacombe Prize of TMS (2015). He is a highly-cited author of ISI, a fellow of ASM, IOP and TMS, and has co-authored more than 200 publications and two books.

Official source

Related concepts (32)

Phase diagram

A phase diagram in physical chemistry, engineering, mineralogy, and materials science is a type of chart used to show conditions (pressure, temperature, volume, etc.) at which thermodynamically distinct phases (such as solid, liquid or gaseous states) occur and coexist at equilibrium. Common components of a phase diagram are lines of equilibrium or phase boundaries, which refer to lines that mark conditions under which multiple phases can coexist at equilibrium. Phase transitions occur along lines of equilibrium.

Phase (matter)

In the physical sciences, a phase is a region of material that is chemically uniform, physically distinct, and (often) mechanically separable. In a system consisting of ice and water in a glass jar, the ice cubes are one phase, the water is a second phase, and the humid air is a third phase over the ice and water. The glass of the jar is another separate phase. (See .) More precisely, a phase is a region of space (a thermodynamic system), throughout which all physical properties of a material are essentially uniform.

Phase rule

In thermodynamics, the phase rule is a general principle governing "pVT" systems, whose thermodynamic states are completely described by the variables pressure (p), volume (V) and temperature (T), in thermodynamic equilibrium. If F is the number of degrees of freedom, C is the number of components and P is the number of phases, then It was derived by American physicist Josiah Willard Gibbs in his landmark paper titled On the Equilibrium of Heterogeneous Substances, published in parts between 1875 and 1878.

Unary numeral system

The unary numeral system is the simplest numeral system to represent natural numbers: to represent a number N, a symbol representing 1 is repeated N times. In the unary system, the number 0 (zero) is represented by the empty string, that is, the absence of a symbol. Numbers 1, 2, 3, 4, 5, 6, ... are represented in unary as 1, 11, 111, 1111, 11111, 111111, ... Unary is a bijective numeral system.

Numeral system

A numeral system is a writing system for expressing numbers; that is, a mathematical notation for representing numbers of a given set, using digits or other symbols in a consistent manner. The same sequence of symbols may represent different numbers in different numeral systems. For example, "11" represents the number eleven in the decimal numeral system (today, the most common system globally), the number three in the binary numeral system (used in modern computers), and the number two in the unary numeral system (used in tallying scores).

Related lectures (64)

Phase Diagrams: Understanding Materials Properties

Explores phase diagrams, solubility, latent heat, and Gibbs Phase Rule in materials science.

Thermodynamic Modeling: Real Solutions

Explores thermodynamic modeling of real solutions in materials science, focusing on regular and sublattice models.

Binary Systems: Phases and Miscibility

Explores binary systems, phases, and miscibility in different components, emphasizing the importance of understanding phase relationships.

Phase Diagrams: Understanding Materials Science

Explores phase diagrams in materials science, covering phase transitions, system composition, solvents, and solutes.

Phase Separations in Polymer Solutions

Explores phase separations in polymer solutions, covering colloids, liquid crystals, miscibility, phase diagrams, and nucleation mechanisms.

Fabien Sorin

Sep 2002-Oct 2007 Ph.D., Department of Materials Science and Engineering, MIT, USA. Supervisor: Prof. Yoel Fink; Thesis: Multi-material, Multifunctional Fiber Devices. After graduating with an engineering degree and a Master of Science in Physics from the Ecole Polytechnique in Palaiseau, France, Prof. Sorin joined the department of Materials Science and Engineering at the Massachusetts Institute of Technology (MIT) in Cambridge, USA for his graduate studies. He worked as a research assistant in the Photonic Bandgap Fibers and Devices Group of Professor Yoel Fink and graduated with a PhD in 2008. His PhD thesis led to the development of a new class of fiber material and devices and he was a pioneer of the field of multi-material fibers. Mar 2008-Oct 2010 Postdoctoral Associate and Research Scientist, Research Laboratory of Electronics, MIT. He then joined the Research Laboratory of Electronics at MIT as a Postdoctoral Associate, and continued as a Research Scientist associate, where he conducted independent research in the emerging field of multi-material fibers and was involved and led a variety of projects in fundamental research as well as in collaborations with local start-ups. Apr 2011 Feb 2013 Research Engineer, Saint-Gobain Recherche, Aubervilliers, France. Surface du Verre et interface Group In 2011, prof. Sorin returned to Europe and joined the company Saint-Gobain in the Saint-Gobain Recherche center, its biggest research center located near Paris in France. As a research engineer, he developed a new research thrust investigating new photonic materials and nanostructures for the energy and building industries. In particular, he and colleagues developed innovative processing approaches to deploy photonic nanostructures for light management over large area substrates, for applications in energy harvesting and saving, and for building materials and windows. Mar 2013 Present Assistant Professor tenure-track, Ecole Polytechnique Fédérale de Lausanne (EPFL), Switzerland. Head of the Photonic materials and fibre devices laboratory (FIMAP) Since March 2013, he is in the department of Materials Science (IMX) at the Ecole Polytechnique Fédérale de Lausanne (EPFL) as an assistant professor tenure-track. He is starting a research group on photonic materials and fiber devices (FIMAP), continuing on developing innovative materials processing approaches and photonic device architectures to develop new solutions in energy harvesting, saving and storage, in sensing and monitoring, health care and smart fabrics.

Related concepts (32)